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Lecture Demonstrations in Physical Chemistry

Lecture Demonstrations in Physical Chemistry


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This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1919 Excerpt: ...solution is made very slightly alkaline with ammonia, so as to make sure that it contains no free acid (hydrolysis is likely to cause a slight acidity). It is then poured into an aqueous solution of ammonia, colored by phenolphthalein. The red color fades to a scarcely perceptible pink. VI. Hydrolysis. The slight ionization of water (according to Kohlrausch and Heydweiller2 the degree of dissociation for H" and OH'-ions, expressed in gram equivalents per liter is 1.05 times i0--7 at 250) accounts for the hydrolysis 0f 1 Analytische Chemie, 7- Aufl., p. 311, (1911).! Zeitschr. f. phys. Chem., 14, p. 317, (1894). ELECTROCHEMISTRY Alrff VoNttf-tf AB0fcV " "iOI" salts, viz., the decomposing effect of water on dissolved salts. The salts of a strong base and a strong acid are not appreciably hydrolyzed; the solutions show a neutral reaction. However, under exceptional conditions, water is able to decompose for example sodium chloride, according to the equation: NaCl + HOH = NaOH + HC1. 110. The following experiment demonstrates this decomposition.1 A platinum crucible is heated in a blast lamp or over a Meker burner to a bright yellow heat (ii000) and a small quantity of sodium chloride (melting point 8840) fused in the crucible. One cubic centimeter of water is dropped from a pipette drop by drop on the fused salt. When half of the water has been evaporated, which takes about 30 seconds, the remaining aqueous solution is poured off into a beaker containing a blue litmus solution which turns red. After the crucible has cooled down the residual salt is dissolved in water, and the solution poured into a solution of red litmus which changes into blue. 111. Salts of weak acids with strong bases, show an alkaline reaction, readily detected by ...


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Product Details
  • ISBN-13: 9781152368545
  • Publisher: Rarebooksclub.com
  • Publisher Imprint: Rarebooksclub.com
  • Height: 246 mm
  • No of Pages: 44
  • Spine Width: 2 mm
  • Width: 189 mm
  • ISBN-10: 1152368540
  • Publisher Date: 01 May 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Weight: 95 gr


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