Molecular Physics and Elements of Quantum Chemistry: Introduction to Experiments and Theory(Advanced Texts in Physics)

Since the publication of the first edition of this book, there have been many im­ portant new developments in the field of molecular physics. The new methods and results which are most significant for students are treated extensively in this second edition. Among these are in particular single-molecule spectroscopy and the field of molecular electronics, which is in a stage of rapid development, including the areas of electroluminescence and organic light-emitting diodes. In addition, we have ex­ tended and corrected the earlier material in a number of places. We have also included exercises in this new edition; they will allow students to deepen their understanding and offer a basis for further individual study. The complete solutions to the exercises can be found on the Internet under www. springeronline. com/3-540-40792-S. We are grateful to Mr. C. -D. Bachem and Dr. Th. Schneider of the Springer­ Verlag for their continuous and very agreeable cooperation during the preparation of the book. We thank our colleague Prof. W. D. Brewer for his competent translation. Stuttgart, February 2004 H. Haken . H. C. Wolf Preface to the First Edition This textbook is intended for use by students of physics, physical chemistry, and theoretical chemistry. The reader is presumed to have a basic knowledge of atomic and quantum physics at the level provided, for example, by the first few chapters in our book The Physics of Atoms and Quanta.

Table of Contents:
1 Introduction.- 2 Mechanical Properties of Molecules, Their Size and Mass.- 3 Molecules in Electric and Magnetic Fields.- 4 Introduction to the Theory of Chemical Bonding.- 5 Symmetries and Symmetry Operations: A First Overview.- 6 Symmetries and Symmetry Operations. A Systematic Approach.- 7 The Multi-Electron Problem in Molecular Physics and Quantum Chemistry.- 8 Overview of Molecular Spectroscopy Techniques.- 9 Rotational Spectroscopy.- 10 Vibrational Spectroscopy.- 11 The Quantum-Mechanical Treatment of Rotational and Vibrational Spectra.- 12 Raman Spectra.- 13 Electronic States.- 14 The Electronic Spectra of Molecules.- 15 Further Remarks on the Techniques of Molecular Spectroscopy.- 16 The Interaction of Molecules with Light: Quantum-Mechanical Treatment.- 17 Theoretical Treatment of the Raman Effect and the Elements of Nonlinear Optics.- 18 Nuclear Magnetic Resonance.- 19 Electron Spin Resonance.- 20 Macromolecules, Biomolecules, and Supermolecules.- 21 Experiments on and withSingle Molecules.- 22 Molecular Electronics and Other Applications.- A. 1 The Calculation of Expectation Values Using Wavefunctions Represented by Determinants.- A.l.l Calculation of Determinants.- A.1.2 Calculation of Expectation Values.- A.2 Calculation of the Density of Radiation.- Fundamental Constants of Atomic Physics (Inside Front Cover).- Energy Conversion Table (Inside Back Cover).

Review :
From the reviews: "The presentation is self-contained and logical, often with excellent illustrations chosen with care ... The perspective is fresh and well suited to the current interest in materials science ... I recommend the book and have used it as independent reading for our majors in physical chemistry." Zoltàn Géza Soos, Physics Today, 2/1997 From the reviews of the second edition: "The present textbook concerns itself with two inseparably connected themes: chemical bonding and the physical properties of molecules. … Each chapter ends with a set of problems … . The bibliography contains numerous and up to date references to the original literature. … I recommend this book unreservedly for its high pedagogical value, more specially to the students starting their Mater degree (1ère licence)." (Freddy Binon, Physicalia, Vol. 57 (3), 2005)