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Home > Sciences & Environment > Earth sciences > Geology, geomorphology and the lithosphere > Untersuchungen Zur Abiotischen Bildung Von Acetonitril, Haloacetonitrilen Und Trichlornitromethan
Untersuchungen Zur Abiotischen Bildung Von Acetonitril, Haloacetonitrilen Und Trichlornitromethan

Untersuchungen Zur Abiotischen Bildung Von Acetonitril, Haloacetonitrilen Und Trichlornitromethan


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About the Book

Acetonitril, halogenierte Acetonitrile und Trichlornitromethan besitzen vom toxikologischen Standpunkt aus ein hohes Gefahrdungspotenzial fur die Umwelt. Nichtsdestotrotz herrscht in der Wissenschaft eine grosse Unkenntnis uber die Entstehung, den Transport, die Verbreitung und die moglichen Abbaumechanismen dieser Verbindungen. Dies betrifft vor allem die chlorierten und bromierten Acetonitrile sowie Trichlornitromethan in der Pedosphare. Acetonitril gelangt nach neuesten Untersuchungen hauptsachlich auf naturlichem Wege in die Umwelt. Die dominante Quelle ist hierbei in der Verbrennung von Biomasse ('biomass burning') zu sehen (Hamilton et al., 2004). Auf diese Weise kommt es durch atmospharischen Transport zu einer ubiquitaren Verbreitung von Acetonitril in der Atmosphare. Aus diesem Grund dient Acetonitril in vielen Computermodellen als atmospharisches Tracergas fur biomass burning (Sanhueza et al., 2004). Uber bromierte und chlorierte Acetonitrile sowie Trichlornitromethan wurde bisher fast ausschliesslich im Zusammenhang mit der Chlorierung von Trink- und Badewasser berichtet (z.B. Scholer u. Schopp, 1984; Nikolaou et al., 1999), weswegen sie in die Stoffklasse der Desinfektionsnebenprodukte eingeordnet werden, wobei von einigen dieser Verbindungen ein toxisches Gefahrdungspotenzial fur die Umwelt ausgeht. Uber die mogliche Bildung der genannten Verbindungen in Boden gibt es hingegen bisher kaum Daten in der wissenschaftlichen Literatur. Die wenigen Publikationen, die hierzu bekannt sind, beschaftigen sich dabei nur am Rande mit Bodenprozessen bei denen Acetonitril, chlorierte und bromierte Acetonitrile sowie Trichlornitromethan gebildet oder abgebaut werden. Aus den oben angefuhrten Grunden ist es notwendig zu untersuchen, ob und in welcher Form diese zuvor erwahnten organischen Verbindungen gebildet werden konnen


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Product Details
  • ISBN-13: 9783638383431
  • Publisher: Grin Verlag
  • Publisher Imprint: Grin Verlag
  • Language: German
  • ISBN-10: 3638383431
  • Publisher Date: 01 Jan 2005
  • Binding: Digital (delivered electronically)
  • No of Pages: 101


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