Buy Nuclear Magnetic Resonance Spectroscopy of Boron Compounds
Book 1
Book 2
Book 3
Book 1
Book 2
Book 3
Book 1
Book 2
Book 3
Book 1
Book 2
Book 3
Home > Mathematics and Science Textbooks > Chemistry > Analytical chemistry > Nuclear Magnetic Resonance Spectroscopy of Boron Compounds: (14 NMR Basic Principles and Progress)
Nuclear Magnetic Resonance Spectroscopy of Boron Compounds: (14 NMR Basic Principles and Progress)

Nuclear Magnetic Resonance Spectroscopy of Boron Compounds: (14 NMR Basic Principles and Progress)


     0     
5
4
3
2
1



Out of Stock


Notify me when this book is in stock
X
About the Book

The revolutionary impetus of the NMR methods in organic chemistry has parallels in the field of boron chemistry. lIB NMR spectroscopy provided a basis for the elucida- tion of structures and reactions of the boron hydrides. However, although many studies have been carried out with the higher boranes, carboranes, metalloboranes, etc. , and although certain patterns have emerged, the correlation between the observed chemical shift and the assigned structural unit is still not fully understood. Therefore, predictions in this area are still rather limited, and semiquantitative interpretations are not yet pos- sible. Several years ago Eaton and Lipscomb sUpImarized the status in this field in their book "NMR Studies of Boron Hydrides and Related Compounds" and a plethora of new data has accumulated since then. The book also contained material on simple bo- rane derivatives, but they were not discussed in any detail. On the other hand many systematic studies, both synthetic and spectroscopic, have been conducted on these simple boron materials in the last decade. Thus a large amount of NMR information is available, not only on lIB but also on 1 H, 1 3 C, and 14 N. However, this information is widely scattered in the literature, and often the data are not discussed at all. It see- med appropriate, therefore, to collect these data and to present them in one volume.

Table of Contents:
1 Introduction and Scope.- 1.1. Application of 11 B NMR Spectroscopy.- 1.1.1. Investigation of Structures.- 1.1.2. Investigation of Reactions.- 1.1.3. Application in Analysis.- 1.2. Scope.- Literature to Chapter 1.- 2 Nuclear Magnetic Properties of Boron.- 2.1. The Isotopes 10 B,11 B.- 2.2. Information from Boron NMR Data.- 2.2.1. Chemical Shifts.- 2.2.2. Coupling Constants between Boron and Other Nuclei.- 2.2.3. Relaxation and Line Width.- 2.2.4. Paramagnetic Compounds.- 2.2.5. Exchange Processes.- 2.3. Chemical Shifts.- 2.3.1. Theory of Chemical Shifts.- 2.3.2. Empirical Correlations of 11 B Chemical Shifts.- 2.3.3. Semiempirical Calculations.- 2.4. Spin-Spin Coupling.- 2.4.1. Theory of Spin-Spin Coupling.- 2.4.2. Empirical and Semiempirical Correlation of Coupling Constants 1 J(11 BX).- Literature to Chapter 2.- 3 11B NMR of Two-Coordinate Boron.- 4 11B Chemical Shifts of Three-Coordinate Boron.- 4.1. Survey of Substituent Effects.- 4.1.1. ?- and ?-Bonding Effects.- 4.1.2. Anisotropy Effects.- 4.1.3. Effects of Ring Size and Steric Hindrance.- 4.2. Triorganylboranes.- 4.2.1. Trialkylboranes.- 4.2.2. Carbon-Substituted Trialkylboranes.- 4.2.3. Unsaturated Triorganylboranes-Site of Unsaturation Adjacent to Boron.- 4.3. Halogenoboranes.- 4.3.1. Trihalogenoboranes.- 4.3.2. Halogeno(organyl)boranes.- 4.3.3. Pseudohalogenoboranes and Pseudohalogeno(organyl)boranes.- 4.4. Boranes with Boron-Oxygen Bonds.- 4.4.1. Esters of Boric Acid and Organylboric Acids.- 4.4.2. Boroxines.- 4.4.3. Halogeno(organyloxo)boranes and Halogenoorganyl(organyloxo)-boranes.- 4.5. Boranes with Boron-Sulfur Bonds.- 4.5.1. Tris(organylthio)boranes and Organyl(organylthio)boranes.- 4.5.2. Borthiines.- 4.5.3. Organylthioboranes Containing B-C, B-O, B-Halogen Bonds.- 4.6. Boranes with Boron-Selenium Bonds.- 4.7. Boranes with Boron-Nitrogen Bonds.- 4.7.1. Monoaminoboranes.- 4.7.1.1. Aminoorganylboranes.- 4.7.1.2. Cyclic Monoamino(organyl)boranes.- 4.7.1.3. B-Functional Monoaminoboranes.- 4.7.1.4. N-Substituted Monoaminodiorganylboranes.- 4.7.1.5. B,N-Functional Monoaminoboranes.- 4.7.2. Bis(amino)boranes.- 4.7.2.1. Bis(amino)organylboranes.- 4.7.2.2. B-Functional Bis(amino)boranes.- 4.7.2.3. N-Functional Bis(amino)boranes.- 4.7.2.4. B,N-Functional Bis(amino)boranes.- 4.7.3. Tris(amino)boranes.- 4.7.4. Diborylamines and Triborylamines.- 4.7.4.1. Bis(diorganylboryl)amines and Tris(diorganylboryl)amines.- 4.7.4.2. B-Substituted Diborylamines.- 4.7.5. Ketimino and Aldimino Boranes.- 4.7.6. Hydrazino(organyl)boranes.- 4.7.7. Diazaboracycloalkanes.- 4.7.7.1. Diazaborolidines.- 4.7.7.2. Diazaborinanes and Higher Homologues.- 4.7.8. Borazines.- 4.7.9. Six-Membered Boron Nitrogen Heterocycles Derived from Borazines Containing Heteroatoms Other than Carbon.- 4.7.10. BN Isoconjugate Cyclic Polyenes.- 4.7.11. Boron Heterocycles Containing a Hydrazino Group.- 4.7.11.1. 1,2,4,3,5-Triazadiborolidines.- 4.7.11.2. Hexahydro-Tetrazadiborines.- 4.7.11.3. Boron Heterocycles Containing a Hydrazino Group and Ring Atoms Other than Boron.- 4.7.12. 1,2,3,4,5-Tetrazaborolines(2).- 4.7.13. Four-and Eight-Membered BN Heterocycles.- 4.8. Diboron and Polyboron Compounds.- 4.9. Boranes with Boron-Hydrogen Bonds.- 4.10. Boranes with Boron-Silicon, Boron-Germanium, Boron-Tin, and Boron-Lead Bonds.- 5 11B NMR of Transition Metal Boron Compounds.- 6 11B NMR of Diborane and Derivatives.- 6.1. Diborane.- 6.2. Organyldiboranes.- 6.3. -Substituted Diboranes.- 6.4. Heptahydrodiborates and -Substituted Derivatives.- 7 11B NMR of Tetracoordinate Boron.- 7.1. Metal Tetrahydroborates.- 7.1.1. Alkali Metal Tetrahydroborates.- 7.1.2. Alkaline Earth Metal Tetrahydroborates.- 7.1.3. Aluminium Tetrahydroborates.- 7.1.4. Transition Metal Tetrahydroborates.- 7.2. Substituted Metal Tetrahydroborates.- 7.3. Metal Borates MBX4 and [BX4-nYn].- 7.3.1. Metal Tetraorganylborates.- 7.3.2. Metal Halogenoborates.- 7.3.3. Metal Borates with Various Substituents.- 7.4. Donor-Acceptor Complexes.- 7.4.1. Survey of Donor-Acceptor Properties.- 7.4.2. Boron Adducts with Oxygen Donors.- 7.4.3. Boron Adducts with Sulfur and Selenium Donors.- 7.4.4. Boron Adducts with Nitrogen Donors.- 7.4.4.1. Boron Adducts with Tetracoordinate Nitrogen.- 7.4.4.2. Boron Adducts with Three-Coordinate Nitrogen.- 7.4.4.3. Boron Adducts with Two-Coordinate Nitrogen.- 7.4.5. "Boronium" Salts [Bis(amine)dihydroboron]-Cations.- 7.4.6. "Chelate Complexes".- 7.4.7. Borane Adducts with Phosphorous Donors.- 7.4.7.1. BH3 Adducts of Phosphines.- 7.4.7.2. Organylborane Phosphines.- 7.4.7.3. Trihalogenoborane Phosphines.- 7.4.7.4. Halogeno(hydrido)borane and Halogeno(organyl)borane Phosphines.- 7.4.7.5. Phosphine Adducts of Mixed Substituted Boranes.- 7.4.7.6. Cyclic Phosphinoboranes.- 7.4.8. Borane Adducts of Arsines and Stibines.- 8 Spin-Spin Coupling Constants nJ(11 BX).- 8.1. Spin-Spin Coupling Between Boron and Hydrogen.- 8.2. Boron-Boron Coupling Constants.- 8.3. Coupling Constants of Boron and Group IV Elements.- 8.3.1. Spin-Spin Coupling Between Boron and Carbon.- 8.3.2. Spin-Spin Coupling Between Boron and Silicon, Tin, and Lead.- 8.4. Spin-Spin Coupling Between Boron and Group V Elements.- 8.4.1. Spin-Spin Coupling Between Boron and Nitrogen.- 8.4.2. Spin-Spin Coupling Between Boron and Phosphorus.- 8.5. Coupling Between Boron and Group VI Elements.- 8.6. Coupling Between Boron and Fluorine.- 8.7. Spin-Spin Coupling Between Boron and Transition Metals.- 9 Tables of 11B-NMR Data.- 9.1. Remarks on the Organization of the Tables.- 9.2. List of Tables, Including Structural Symbols.- 9.3. Tables.- 9.4. CA Formula Index.- References.- Author Index.


Best Sellers


Product Details
  • ISBN-13: 9783540084563
  • Publisher: Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
  • Publisher Imprint: Springer-Verlag Berlin and Heidelberg GmbH & Co. K
  • Language: English
  • Series Title: 14 NMR Basic Principles and Progress
  • ISBN-10: 3540084568
  • Publisher Date: 01 May 1978
  • Binding: Hardback
  • Returnable: N
  • Weight: 880 gr


Similar Products

Add Photo
Add Photo

Customer Reviews

REVIEWS      0     
Click Here To Be The First to Review this Product
Nuclear Magnetic Resonance Spectroscopy of Boron Compounds: (14 NMR Basic Principles and Progress)
Springer-Verlag Berlin and Heidelberg GmbH & Co. KG -
Nuclear Magnetic Resonance Spectroscopy of Boron Compounds: (14 NMR Basic Principles and Progress)
Writing guidlines
We want to publish your review, so please:
  • keep your review on the product. Review's that defame author's character will be rejected.
  • Keep your review focused on the product.
  • Avoid writing about customer service. contact us instead if you have issue requiring immediate attention.
  • Refrain from mentioning competitors or the specific price you paid for the product.
  • Do not include any personally identifiable information, such as full names.

Nuclear Magnetic Resonance Spectroscopy of Boron Compounds: (14 NMR Basic Principles and Progress)

Required fields are marked with *

Review Title*
Review
    Add Photo Add up to 6 photos
    Would you recommend this product to a friend?
    Tag this Book Read more
    Does your review contain spoilers?
    What type of reader best describes you?
    I agree to the terms & conditions
    You may receive emails regarding this submission. Any emails will include the ability to opt-out of future communications.

    CUSTOMER RATINGS AND REVIEWS AND QUESTIONS AND ANSWERS TERMS OF USE

    These Terms of Use govern your conduct associated with the Customer Ratings and Reviews and/or Questions and Answers service offered by Bookswagon (the "CRR Service").


    By submitting any content to Bookswagon, you guarantee that:
    • You are the sole author and owner of the intellectual property rights in the content;
    • All "moral rights" that you may have in such content have been voluntarily waived by you;
    • All content that you post is accurate;
    • You are at least 13 years old;
    • Use of the content you supply does not violate these Terms of Use and will not cause injury to any person or entity.
    You further agree that you may not submit any content:
    • That is known by you to be false, inaccurate or misleading;
    • That infringes any third party's copyright, patent, trademark, trade secret or other proprietary rights or rights of publicity or privacy;
    • That violates any law, statute, ordinance or regulation (including, but not limited to, those governing, consumer protection, unfair competition, anti-discrimination or false advertising);
    • That is, or may reasonably be considered to be, defamatory, libelous, hateful, racially or religiously biased or offensive, unlawfully threatening or unlawfully harassing to any individual, partnership or corporation;
    • For which you were compensated or granted any consideration by any unapproved third party;
    • That includes any information that references other websites, addresses, email addresses, contact information or phone numbers;
    • That contains any computer viruses, worms or other potentially damaging computer programs or files.
    You agree to indemnify and hold Bookswagon (and its officers, directors, agents, subsidiaries, joint ventures, employees and third-party service providers, including but not limited to Bazaarvoice, Inc.), harmless from all claims, demands, and damages (actual and consequential) of every kind and nature, known and unknown including reasonable attorneys' fees, arising out of a breach of your representations and warranties set forth above, or your violation of any law or the rights of a third party.


    For any content that you submit, you grant Bookswagon a perpetual, irrevocable, royalty-free, transferable right and license to use, copy, modify, delete in its entirety, adapt, publish, translate, create derivative works from and/or sell, transfer, and/or distribute such content and/or incorporate such content into any form, medium or technology throughout the world without compensation to you. Additionally,  Bookswagon may transfer or share any personal information that you submit with its third-party service providers, including but not limited to Bazaarvoice, Inc. in accordance with  Privacy Policy


    All content that you submit may be used at Bookswagon's sole discretion. Bookswagon reserves the right to change, condense, withhold publication, remove or delete any content on Bookswagon's website that Bookswagon deems, in its sole discretion, to violate the content guidelines or any other provision of these Terms of Use.  Bookswagon does not guarantee that you will have any recourse through Bookswagon to edit or delete any content you have submitted. Ratings and written comments are generally posted within two to four business days. However, Bookswagon reserves the right to remove or to refuse to post any submission to the extent authorized by law. You acknowledge that you, not Bookswagon, are responsible for the contents of your submission. None of the content that you submit shall be subject to any obligation of confidence on the part of Bookswagon, its agents, subsidiaries, affiliates, partners or third party service providers (including but not limited to Bazaarvoice, Inc.)and their respective directors, officers and employees.

    Accept

    Fresh on the Shelf


    Inspired by your browsing history


    Your review has been submitted!

    You've already reviewed this product!