Dipole-Quadrupole Theory of Surface Enhanced Raman Scattering
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Dipole-Quadrupole Theory of Surface Enhanced Raman Scattering

Dipole-Quadrupole Theory of Surface Enhanced Raman Scattering


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Table of Contents:
Preface; Introduction; Main Specific Features of the SERS phenomenon; Some of the Existing Theories; Some Properties of the Electromagnetic Field Near a Rough Metal Surface; Expressions for the SER Cross-Sections of Arbitrary and Symmetrical Molecules; Selection Rules For Symmetrical Molecules; Classification of the Contributions by the Degree of Enhancement; Most Enhanced Bands in SERS; (dz-Qmain), (Qmain-dz) and (dz-dz) Contributions and Appearance of Forbidden Bands in the SER Spectra of Symmetrical Molecules; Contributions Caused by One Minor and One Main Moments; Disturbance of the Symmetry of Molecules Upon Adsorption and Two Possible Mechanisms of the Appearance of Forbidden Bands in the SER Spectra; Analysis of the SER Spectra; Analysis of the SER Spectra of Molecules With and Symmetry Groups; Anomalies in the SER Spectra of Benzene Adsorbed on Lithium and Hexafluorobenzene Adsorbed on Silver; Electrodynamic Forbiddance of the Quadrupole Enhancement Mechanism in Molecules with Cubic Symmetry Groups; Discussion of Experimental Results; About the Electrodynamic Forbiddance of the Quadrupole SERS Mechanism in Other Molecules; Anomalies of the SER Spectra of Symmetrical Molecules Adsorbed on Transition Metal Substrates; Possible Reason of the Competition of the Raman Bands (Influence of the Complex Dielectric Constant); Single Molecule Detection by the SERS Method and Its Relation to the Quadrupole SERS Theory; Charge Transfer Enhancement Mechanism; Explanation of Experimental Phenomena Accompanying SERS; Conclusion; Appendix 1 Wave functions of Arbitrary Molecules; Appendix 2 The Tables of Irreducible Representations of Some Point Groups; References; Index.


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Product Details
  • ISBN-13: 9781606925799
  • Publisher: Nova Science Publishers Inc
  • Publisher Imprint: Nova Science Publishers Inc
  • Height: 180 mm
  • No of Pages: 136
  • Weight: 326 gr
  • ISBN-10: 1606925792
  • Publisher Date: 05 May 2009
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Width: 260 mm

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