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Home > Mathematics and Science books > Chemistry > Design, Synthesis and Characterization of Metal Complexes of D⁶ And D⁰ Electronic Configuration and Their Inorganic-Organic Hybrids: From Covalent Conjugation to Supramolecular Assembly and Luninescence Chemosensing
Design, Synthesis and Characterization of Metal Complexes of D⁶ And D⁰ Electronic Configuration and Their Inorganic-Organic Hybrids: From Covalent Conjugation to Supramolecular Assembly and Luninescence Chemosensing

Design, Synthesis and Characterization of Metal Complexes of D⁶ And D⁰ Electronic Configuration and Their Inorganic-Organic Hybrids: From Covalent Conjugation to Supramolecular Assembly and Luninescence Chemosensing


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This dissertation, "Design, Synthesis and Characterization of Metal Complexes of D⁶ and D⁰ Electronic Configuration and Their Inorganic-organic Hybrids: From Covalent Conjugation to Supramolecular Assembly and Luninescence Chemosensing" by Chi-ming, Frankie, Leung, 梁志明, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Abstract of thesis entitled DESIGN, SYNTHESIS AND CHARACTERIZATION OF METAL COMPLEXES 6 10 OF d AND d ELECTRONIC CONFIGURATION AND THEIR INORGANIC-ORGANIC HYBRIDS - FROM COVALENT CONJUGATION TO SUPRAMOLECULAR ASSEMBLY AND LUMINESCENCE CHEMOSENSING Submitted by LEUNG CHI MING, FRANKIE for the Degree of Doctor of Philosophy at The University of Hong Kong in January 2015 6 10 Various classes of transition metal complexes with d and d electronic configuration and their inorganic-organic hybrids have been prepared and employed for molecular recognition studies. A series of crown ether-based bis-alkynyl-bridged gold(I) complexes have been designed, synthesized and characterized. The alkali metal cation-binding properties of the complexes have been studied by UV-vis, emission, H NMR and ESI-mass spectroscopy. The binding of K has switched "on" or "off" the emission associated with intramolecular aurophilic interaction of the complexes upon formation of the ion-bound adducts in a sandwich fashion. Various spacers between the two crown ether units were found to affect the binding affinities. In addition, a tetranuclear alkynylgold(I) complex with four amide groups has been successfully synthesized and characterized. The photoluminescence of the complex has been switched on upon the binding of cadmium ion due to the suppression of photo-induced electron transfer (PET) and rigidification of the molecule. The binding mode has been studied by 2D NOESY H NMR experiments. By combining the advantages of supramolecular chemistry and nanotechnology, the conjugation of transition metal complexes to gold nanoparticles (GNPs) has been studied. A number of lipoic acid-containing ruthenium(II) and rhenium(I) bipyridine complexes have been synthesized and characterized. Covalent functionalization of GNPs with these complexes has resulted in interesting supramolecular assemblies with Forster resonance energy transfer (FRET) properties that could be modulated via esterase hydrolysis. The enzymatic activity has been determined by Michaelis-Menten kinetics. The quenching mechanism has also been studied by transient absorption and time-resolved emission decay measurements. Besides, a number of adamantane-containing Ru(II) and Re(I) complexes have been synthesized and characterized. These complexes were non-covalently functionalized with the β-cyclodextrin capped gold nanoparticles (β-CD-GNPs) through the host-guest interaction between cyclodextrin and adamantine, which were characterized by using 2D ROESY H NMR experiments. The FRET properties of the conjugates could be modulated via both esterase hydrolysis and competitive displacement of steroid. The FRET efficiencies were found to vary with the nature of the chromophores and the length of the spacer between the transition metal complexes and the GNPs. In addition, the conjugation of transition metal complexes to various anisotropic nano-materials has also been studied. A bis-adamantane-containing Re(I) complex has been synthesized and characterized. The complex was found to induce the "end-to-end" assembly of cyclodextrin-end-modified gold nanorods (β-CD-GNRs) of different aspect ratios, which have been characterized by transmiss


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Product Details
  • ISBN-13: 9781361025239
  • Publisher: Open Dissertation Press
  • Publisher Imprint: Open Dissertation Press
  • Height: 279 mm
  • No of Pages: 430
  • Sub Title: From Covalent Conjugation to Supramolecular Assembly and Luninescence Chemosensing
  • Width: 216 mm
  • ISBN-10: 1361025239
  • Publisher Date: 26 Jan 2017
  • Binding: Paperback
  • Language: English
  • Spine Width: 22 mm
  • Weight: 989 gr


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Design, Synthesis and Characterization of Metal Complexes of D⁶ And D⁰ Electronic Configuration and Their Inorganic-Organic Hybrids: From Covalent Conjugation to Supramolecular Assembly and Luninescence Chemosensing
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Design, Synthesis and Characterization of Metal Complexes of D⁶ And D⁰ Electronic Configuration and Their Inorganic-Organic Hybrids: From Covalent Conjugation to Supramolecular Assembly and Luninescence Chemosensing
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