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Outlines of Theoretical Chemistry

Outlines of Theoretical Chemistry


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This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1892 Excerpt: ...63. Heterogeneous Solid Molecular Aggregates.--A solid body may also be produced by the grouping together of different kinds of molecules. Many substances crystallise with water of crystallisation; still these compounds would appear rather to be homogeneous aggregates, for every molecule is united with a definite number of molecules of water, and the molecules so produced are regularly grouped into new and larger ones! A few only of the compounds containing water crystallise in the regular system: as, for instance, the alums, the twenty-four molecules of water being so arranged around the salt molecule as to produce an aggregate homogeneous in all directions. The so-called double salts are similarly constituted to the compounds containing water of crystallisation, and these must be reckoned amongst the homogeneous aggregates, and also all other combinations produced in accordance with the laws of stoechiometry. The mixed crystals of isomorphous bodies in which the constituents occur in varying and changing proportions must, on the other hand, be considered as heterogeneous aggregates. Thus, for example, the so-called vitriols, that is, the sulphates of magnesium, copper, zinc, iron, manganese, nickel, and cobalt, crystallising with water of crystallisation, may be crystallised together in any proportions, which is true also of other isomorphous substances. This crystallisation together takes place only when the compounds are of analogous constitution, and when the isomorphous constituent is able to take up approximately the same space. If this condition is not exactly satisfied, then an angle of the crystal of one substance would be altered to a greater or less extent by the entrance into that crystal of another body. For instance, calcspar (CaC03) crystall...


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Product Details
  • ISBN-13: 9781236313713
  • Publisher: Rarebooksclub.com
  • Publisher Imprint: Rarebooksclub.com
  • Height: 246 mm
  • No of Pages: 74
  • Spine Width: 4 mm
  • Width: 189 mm
  • ISBN-10: 1236313712
  • Publisher Date: 01 May 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Weight: 150 gr

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