Buy Electro-Chemistry Volume 1; Part 1. General Theory by Robert Alfred Lehfeldt
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Electro-Chemistry Volume 1; Part 1. General Theory

Electro-Chemistry Volume 1; Part 1. General Theory


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This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1908 Excerpt: ... no accurate information as to the variation of ionisation with constitution. Since, however, it has not yet been found possible to determine K2, this comparison is the only one possible. The numbers quoted from Bredig's paper are affected by another error, for recent work has shown that the value for the mobility of hydroxyl which was used by Bredig in the calculation of A 00 for the bases is too low. Since the order of the ionisation-constants would not be affected by this, and the recalculated numbers would not be the true ionisation-constants, Bredig's numbers are given as they stand. The following conclusions were drawn by Bredig: --The quaternary bases from aliphatic amines are, in general, so strongly ionised that no constant can be obtained. The phosphonium, arsonium, stibonium, sulphonium, and tellurinium bases are also very strongly ionised, but the tin and mercury bases are only weakly ionised. The following numbers are the values of the molecular conductivity of the above-mentioned bases at the dilutions given (T = 250): --These are the true values of the molecular conductivity since all the base is present either as ions, or as non-ionised molecules corresponding to these ions. Secondary bases are more strongly ionised than primary or tertiary bases. K3X, o5 Ammonia 0-0023 Methylamine 0'0500 Dimethylamine 0-0740 Trimethylamine 0-0074 It is, however, quite possible that this is due to the effect of the alkyl group in changing the power of the nitrogen to pass from the trivalent to the pentavalent form by taking up water. Among metamers, constitutive influences have sometimes a very great effect. K3X10' Propylamine o-47 Trimethylamine 0'0074 We should expect this rule to hold, for, leaving out any specific effect of the alkyl group on the ionisation...


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Product Details
  • ISBN-13: 9781236179616
  • Publisher: Rarebooksclub.com
  • Publisher Imprint: Rarebooksclub.com
  • Height: 246 mm
  • No of Pages: 78
  • Spine Width: 4 mm
  • Width: 189 mm
  • ISBN-10: 1236179617
  • Publisher Date: 01 May 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Weight: 154 gr


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