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Elements of Electro-Chemistry; Treated Experimentally

Elements of Electro-Chemistry; Treated Experimentally


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This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1903 Excerpt: ...can be dependent only on the constants of the solvent. Van't Hoff (see Nernst's Theoretical Chemistry English Ed., pp. 126, 128) elucidated the relations between osmotic pressure and the three other magnitudes; and he established the following equations, in which M is the molecular weight, and s is the specific gravity, of the solvent, T0 and T0' are its absolute boiling point and freezing point respectively, w and w' are the latent heat of evaporation and the latent heat of fusion of the solvent per gram, and K, K', and K" are collective constants depending on the solvents used. I. P = Pjza x =ATK atmos. Px M Px II. P = (/-O x W-s-w = y _ K' atmos. III. P=0, -6) x l lbl = (flo = e) K" atmos. Hence it must be possible to find one magnitude from the others. Values for P may be found by applying equations I. and II. to the experimental data which have been tabulated already. The results of doing this are to be seen in the two following tables: --In both tables P (in column 11) is calculated from the equation PV =-0819 T0, or =-0819 T0', litre-atmospheres; where V is the number of litres which would contain one gram-molecule of the substance in solution. Considering that the solutions which were used in determining boiling points and freezing points were, relatively, very concentrated, it is seen that the values thus calculated for P agree very well with those in column 10 which are found by the formula of van't Hoff. It is thus seen that the values found for P from determinations of boiling points and freezing points, which determinations can be accomplished much more accurately than measurements of osmotic pressure, satisfy the equation P V = RT, which corresponds with the gaseous equation; hence the theory of van't Hoff is confirmed afresh by t...


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Product Details
  • ISBN-13: 9781236087379
  • Publisher: Rarebooksclub.com
  • Publisher Imprint: Rarebooksclub.com
  • Height: 246 mm
  • No of Pages: 66
  • Spine Width: 4 mm
  • Width: 189 mm
  • ISBN-10: 1236087372
  • Publisher Date: 01 May 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Weight: 136 gr

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