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The Properties of Electrically Conducting Systems; Including Electrolytes and Metals

The Properties of Electrically Conducting Systems; Including Electrolytes and Metals


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This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1922 Excerpt: ...anions, as well as many anions of organic acids. So far as the degree of ionization is concerned, salts of compound anions exhibit properties similar to those of salts of simple anions. The ionization of the hydrogen derivatives, namely the acids, of such anions, however, is largely dependent upon the nature of the atoms occurring in the anion complex. The introduction of strongly electronegative elements into the anion complex increases the strength, that is, the ionization of the acid. This behavior of the acids is so well known that details need not be introduced here. Certain elementary ions form complex anions with the same or other elements, a more or less complex equilibrium existing among the various complex anions formed in solution. The most common example of a complex anion of this type is the complex iodide ion which is formed by the direct interaction of the iodide ion with iodine, forming the ion I-.I2. The equilibrium in the case of the tri-iodide ion has been extensively studied by a number of investigators. The mean composition of the solution in such cases depends upon the concentration, since the equilibrium between the simple and the complex ion is a function of the concentration.21 It is well known that the halogen salts form various complexes with other halogens, thus indicating that complex anions are formed between a halogen ion of one element with other elements of the halogen group. The chlor-iodides are familiar examples of this type. The equilibrium in the case of these complex anions has not been extensively studied. The work of Kuster22 indicates that the normal sulphide ion reacts with excess sulphur to form a series of complex sulphur anions. These anions appear to be comparable with the complex iodide ion, the charge being a...


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Product Details
  • ISBN-13: 9781236069351
  • Publisher: Rarebooksclub.com
  • Publisher Imprint: Rarebooksclub.com
  • Height: 246 mm
  • No of Pages: 134
  • Spine Width: 7 mm
  • Width: 189 mm
  • ISBN-10: 1236069358
  • Publisher Date: 01 May 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Weight: 254 gr

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