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Home > Art, Film & Photography > Sulle Reazioni Catalitiche (20); Lavoro Premiato Dal R. Istituto Lombardo Di Scienze E Lettere Al Concorso
Sulle Reazioni Catalitiche (20); Lavoro Premiato Dal R. Istituto Lombardo Di Scienze E Lettere Al Concorso

Sulle Reazioni Catalitiche (20); Lavoro Premiato Dal R. Istituto Lombardo Di Scienze E Lettere Al Concorso


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About the Book

Questo libro di storia potrebbe contenere numerosi refusi e parti di testo mancanti. Solitamente gli acquirenti hanno la possibilita di scaricare gratuitamente una copia scansionata del libro originale (senza refusi) direttamente dall'editore. Il libro e Non illustrato. 1906 edition. Estratto: ...fisica. 12. Trattando con cloro il SC si ottiene alla temperatura ordinaria tetracloruro di carbonio, secondo l'equazione: S2C + C1, = CC14 + SC12 ma questi due corpi reagiscono troppo poco. Aggiungendo pero certe sostanze (I, S-bCl5, ecc.) si forma rapidamente CC14. Il Klason che si occupo di queste ricerche isolo molti composti intermedi contenenti C, S, C1. Secondo Scott e preferibile far passare cloro secco nel solfuro di carbonio contenente 2-12 % di iodio disciolto; il bromo ed il pentacloruro di antimonio sarebbero meno efficaci. Se aggiungiamo del ferro molto suddiviso alla miscela di solfuro di carbonio e cloruro di solfo si utilizza meglio il cloro (Miiller e Dabwis). A 60 si inizia spontaneamente la reazione e basta scaldare solo verso la fine dell'operazione; avviene allora la reazione: 2S2C12 + CS2 = CC14 + S6. 13. Ya ricordata anche l'ossidazione della naftalina in acido ftalico coll'acido solforico in presenza di mercurio; questa reazione o una delle molte fasi comprendenti la produzione dell'indaco sintetico. L'aumentato potere ossidante dell'acido solforico quando e presente mercurio od un composto di tale metallo, venne additato da Wiblfarth, or sono alcuni anni, per accelerare l'ossidazione delle sostanze organiche contenenti carbonio nel processo Kjeldahl. In questo caso si mira ad una distruzione completa della materia organica; invece nel caso della naftalina non si ha di mira che un'ossidazione parziale. Riguardo a questa parziale ossidazione, Rosenthal dimostra che l'acido solforico da solo alla temperatura da oltre 200 produce soltanto basi terziarie del gruppo fenilico, partendo dalle ammine aromatiche terziarie, ...


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Product Details
  • ISBN-13: 9781235431814
  • Publisher: Rarebooksclub.com
  • Publisher Imprint: Rarebooksclub.com
  • Height: 246 mm
  • No of Pages: 32
  • Spine Width: 2 mm
  • Width: 189 mm
  • ISBN-10: 1235431819
  • Publisher Date: 01 Oct 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Weight: 82 gr


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