An Elementary Course in Experimental and Analytical Chemistry
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An Elementary Course in Experimental and Analytical Chemistry

An Elementary Course in Experimental and Analytical Chemistry


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About the Book

This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1895 Excerpt: ...than the bromide. To another portion, from each one of the precipitated mixtures, add some solution of sodium thiosulphate. The three precipitates dissolve. Next, stand the remaining portions in bright sunlight. After a time it will be noticed that they darken and become violet in shade. The extent of this darkening can be materially increased by having a slight excess of silver nitrate present in each case, that is, a little more than can be precipitated by the salts added. After the three tubeshave stoodinthe light long enough for their contents to darken throughout, which is aided by shaking occasionally, repeat the experiment of adding sodium thiosulphate. It will now be found that the precipitates have become insoluble. The action of the light has converted them into compounds which can no longer dissolve in a liquid which was a good solvent for the fresh precipitates. The precipitations follow according to these equations: AgN03+NaCl = AgCl+NaN03 AgN03 + NaBr =AgBr+NaN03 AgN03+ KI =AgI +KN03 The experiment shows that in fresh condition these precipitates are soluble in a certain solution, that they are changed in some manner by exposure to light, and that after this change has taken place they are no longer soluble in the solution used. How this fact can be practically applied will be shown below. We need for the purpose what is called sensitive paper, that is, paper which holds on one surface a precipitate as above described. Such a paper may be prepared as follows: Silver Paper. Dissolve a gram of ammonium chloride in 15 Cc. of water, and add about 1 Cc. of alcohol. To this solution add 50 Cc. of white of egg. The white of egg for the purpose is best made by separating the yolk mechanically, and shaking the white portion thoroughly with broken glass...


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Product Details
  • ISBN-13: 9781231012611
  • Publisher: Rarebooksclub.com
  • Publisher Imprint: Rarebooksclub.com
  • Height: 246 mm
  • No of Pages: 132
  • Spine Width: 7 mm
  • Width: 189 mm
  • ISBN-10: 1231012617
  • Publisher Date: 01 May 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Weight: 249 gr


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