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Home > Art, Film & Photography > Thermodynamische Zustandsgrosse: Temperatur, Druck, Innere Energie, Enthalpie, Gibbs-Energie, Entropie, Partialdruck, Freie Energie
Thermodynamische Zustandsgrosse: Temperatur, Druck, Innere Energie, Enthalpie, Gibbs-Energie, Entropie, Partialdruck, Freie Energie

Thermodynamische Zustandsgrosse: Temperatur, Druck, Innere Energie, Enthalpie, Gibbs-Energie, Entropie, Partialdruck, Freie Energie


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About the Book

Dieser Inhalt ist eine Zusammensetzung von Artikeln aus der frei verfugbaren Wikipedia-Enzyklopadie. Seiten: 25. Nicht dargestellt. Kapitel: Temperatur, Druck, Innere Energie, Enthalpie, Gibbs-Energie, Entropie, Partialdruck, Freie Energie, Totalenthalpie, Spezifisches Volumen. Auszug: Die Entropie (griechisches Kunstwort, von - ein, in und - Wendung, Umwandlung) ist eine fundamentale thermodynamische Zustandsgrosse. Sie beschreibt die Zahl der Mikrozustande, durch die der beobachtete Makrozustand des Systems realisiert werden kann. Sie ist eine extensive Zustandsgrosse, jedem Zustand eines thermodynamischen Systems kann also ein Wert der Entropie zugeordnet werden. Die statistische Physik interpretiert diese Zahl als Mass fur das vom System erreichbare Phasenraumvolumen, in der klassischen Thermodynamik sind Gleichgewichtszustande mit gleicher Entropie adiabatisch aquivalent. Dem Gas steht nach dem Entfernen der Zwischenwand ein grosserer Raum zur Verfugung. Es existieren nach der Expansion also mehr Mikrozustande und das System besitzt eine hohere Entropie. Zu Saulen gestapelt sind alle Mikrozustande, die dem System dieselben makroskopischen Eigenschaften verleihenFrei bewegliche Molekule verteilen sich gleichmassig uber einen Raum. Dieser Zustand weist die maximale Entropie auf, oder, anders ausgedruckt, er ist am wahrscheinlichsten. Das lasst sich an vier Molekulen zeigen (Abbildung), die in einem Becherglas standig zwischen der linken und rechten Halfte in Bewegung sind. (Um es auf das Wesentliche zu reduzieren, ist senkrechter Platztausch erst einmal nicht vorgesehen.) Es ergeben sich ganz unterschiedliche und stets wechselnde Verteilungen. In einer Momentaufnahme konnte z.B. nur das zweite Molekul von oben in der rechten Halfte zu sehen sein, die restlichen drei links, in einer anderen die Molekule zwei und drei auf der linken Seite (jeweils grau hervorgehoben). Jede einzelne Aufteilungsvariante - Mikrozustand genannt - ist gleich haufi


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Product Details
  • ISBN-13: 9781159332921
  • Publisher: Books LLC, Wiki Series
  • Publisher Imprint: Books LLC, Wiki Series
  • Height: 246 mm
  • No of Pages: 26
  • Spine Width: 1 mm
  • Weight: 68 gr
  • ISBN-10: 1159332924
  • Publisher Date: 28 Aug 2011
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Sub Title: Temperatur, Druck, Innere Energie, Enthalpie, Gibbs-Energie, Entropie, Partialdruck, Freie Energie
  • Width: 189 mm


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