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Home > Art, Film & Photography > Amide Solvents: Dimethylformamide, Methylpyrrolidone, N-Methylformamide, Dimethylacetamide, 2-Pyrrolidone, N-Vinylpyrrolidone
Amide Solvents: Dimethylformamide, Methylpyrrolidone, N-Methylformamide, Dimethylacetamide, 2-Pyrrolidone, N-Vinylpyrrolidone

Amide Solvents: Dimethylformamide, Methylpyrrolidone, N-Methylformamide, Dimethylacetamide, 2-Pyrrolidone, N-Vinylpyrrolidone


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Chapters: Dimethylformamide, Methylpyrrolidone, N-Methylformamide, Dimethylacetamide, 2-Pyrrolidone, N-Vinylpyrrolidone. Source: Wikipedia. Pages: 26. Not illustrated. Free updates online. Purchase includes a free trial membership in the publisher's book club where you can select from more than a million books without charge. Excerpt: -61 C (212 K) Dimethylformamide is the organic compound with the formula (CH3)2NC(O)H. Commonly abbreviated DMF (though this acronym is sometimes used for dimethylfuran), this colourless liquid is miscible with water and the majority of organic liquids. DMF is a common solvent for chemical reactions. Pure dimethylformamide is odorless whereas technical grade or degraded dimethylformamide often has a fishy smell due to impurity of dimethylamine. Its name is derived from the fact that it is a derivative of formamide, the amide of formic acid. Dimethylformamide is a polar (hydrophilic) aprotic solvent with a high boiling point. It facilitates reactions that follow polar mechanisms, such as SN2 reactions. Dimethylformamide can be synthesized from methyl formate and dimethyl amine or reaction of dimethyl amine and carbon monoxide. Dimethylformamide is not stable in the presence of strong bases like sodium hydroxide or strong acids such as hydrochloric acid or sulfuric acid and is hydrolyzed back into formic acid and dimethylamine, especially at elevated temperatures. Due to the contribution of the two possible resonance structures of an amide, the bond order of the carbonyl C=O bond is reduced, while that of the carbon-nitrogen bond is increased. Thus the infrared spectrum of DMF shows a lower C=O stretching frequency at 1675 cm than an unsubstituted C=O bond. Also, because of the partial double bond character, the rotation about the C-N axis is slow at room temperature, making the two methyl groups inequivalent on the NMR time scale, giving rise to two singlets of 3 protons each at 2.97 and 2.88, ...More: http: //booksllc.net/?id=141513


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Product Details
  • ISBN-13: 9781158330409
  • Publisher: Books LLC
  • Publisher Imprint: Books LLC
  • Height: 152 mm
  • Sub Title: Dimethylformamide, Methylpyrrolidone, N-Methylformamide, Dimethylacetamide, 2-Pyrrolidone, N-Vinylpyrrolidone
  • Width: 229 mm
  • ISBN-10: 1158330405
  • Publisher Date: 15 Sep 2010
  • Binding: Paperback
  • Spine Width: 2 mm
  • Weight: 54 gr


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