Acyl Halides
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Home > Art, Film & Photography > Acyl Halides: Phosphoryl Chloride, Thionyl Fluoride, Acyl Halide, Nitrosyl Fluoride, Sulfuryl Chloride Fluoride, Carbonyl Fluoride
Acyl Halides: Phosphoryl Chloride, Thionyl Fluoride, Acyl Halide, Nitrosyl Fluoride, Sulfuryl Chloride Fluoride, Carbonyl Fluoride

Acyl Halides: Phosphoryl Chloride, Thionyl Fluoride, Acyl Halide, Nitrosyl Fluoride, Sulfuryl Chloride Fluoride, Carbonyl Fluoride


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About the Book

Chapters: Phosphoryl Chloride, Thionyl Fluoride, Acyl Halide, Nitrosyl Fluoride, Sulfuryl Chloride Fluoride, Carbonyl Fluoride, Nitryl Fluoride. Source: Wikipedia. Pages: 26. Not illustrated. Free updates online. Purchase includes a free trial membership in the publisher's book club where you can select from more than a million books without charge. Excerpt: 1.25 C (274.4 K) Phosphoryl chloride (commonly called phosphorus oxychloride) is a colourless liquid with the formula POCl3. It hydrolyses in moist air to phosphoric acid to release choking fumes of hydrogen chloride. It is manufactured industrially on a large scale from phosphorus trichloride and oxygen or phosphorus pentoxide. It is mainly used to make phosphate esters such as tricresyl phosphate. Like phosphate, phosphoryl chloride is tetrahedral in shape. It features three P-Cl bonds and one very strong P=O double bond, with an estimated bond dissociation energy of 533.5 kJ/mol. On the basis of bond length and electronegativity, the Schomaker-Stevenson rule suggests that the double bond form is very dominant (in contrast with POF3). The P=O bond does not resemble the bond in a carbonyl group as in a ketone. The appropriate description of the P-O interaction is a matter of long discussion. Older textbooks favor a description that invokes participation of the d-orbitals on phosphorus. Some of these d-orbitals project toward the O atom, overlapping with p-orbitals on oxygen. More modern texts seem to favor a description where the P-O bonding involves the components of the P-Cl bonds. These descriptions do not consider a role for d-orbitals. where pm = picometers POCl3 reacts with water and alcohols to give hydrogen chloride and phosphoric acid or phosphate esters, respectively: O=PCl3 + 3 H2O O=P(OH)3 + 3 HClIf the water is replaced by an alcohol, the trialkyl phosphate esters result. Such reactions are often performed in the presence of an HCl acceptor such as pyridi...More: http: //booksllc.net/?id=2782231


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Product Details
  • ISBN-13: 9781157589716
  • Publisher: Books LLC
  • Publisher Imprint: Books LLC
  • Height: 152 mm
  • No of Pages: 28
  • Spine Width: 2 mm
  • Weight: 54 gr
  • ISBN-10: 1157589715
  • Publisher Date: 15 Sep 2010
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Sub Title: Phosphoryl Chloride, Thionyl Fluoride, Acyl Halide, Nitrosyl Fluoride, Sulfuryl Chloride Fluoride, Carbonyl Fluoride
  • Width: 229 mm


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