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Home > Art, Film & Photography > Phosphines: Phosphine, Duphos, Dimethylphenylphosphine, Triphos, 1,1-Bis(diphenylphosphino)Methane, Tppts, Diphenylphosphine
Phosphines: Phosphine, Duphos, Dimethylphenylphosphine, Triphos, 1,1-Bis(diphenylphosphino)Methane, Tppts, Diphenylphosphine

Phosphines: Phosphine, Duphos, Dimethylphenylphosphine, Triphos, 1,1-Bis(diphenylphosphino)Methane, Tppts, Diphenylphosphine


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Chapters: Phosphine, Duphos, Dimethylphenylphosphine, Triphos, 1,1-Bis(diphenylphosphino)methane, Tppts, Diphenylphosphine, Chlorodiphenylphosphine, Catacxium F Sulf, Chiraphos, Diphosphines, Xphos, Diphosphane, Sphos, Dichlorophenylphosphine, 1,3-Bis(diphenylphosphino)propane, Dipamp, Dippe. Source: Wikipedia. Pages: 57. Not illustrated. Free updates online. Purchase includes a free trial membership in the publisher's book club where you can select from more than a million books without charge. Excerpt: -132.8 C, 140 K, -207 F Phosphine (IUPAC name: phosphane) is the compound with the chemical formula PH3. It is a colorless, flammable, toxic gas. Pure phosphine is odourless, but technical grade samples have a highly unpleasant odor like garlic or rotting fish, due to the presence of substituted phosphine and diphosphine (P2H4). Phosphines are also a group of organophosphorus compounds with the formula R3P (R = organic derivative). Organophosphines are important in catalysts where they complex to various metal ions; complexes derived from a chiral phosphine can catalyze reactions to give chiral products. Perhaps because of its strong association with elemental phosphorus, phosphine was once regarded as a gaseous form of the element but Lavoisier (1789) recognised it as a combination of phosphorus with hydrogen by describing it as hydruyet of phosphorus, or phosphuret of hydrogen. Th nard (1845) used a cold trap to separate diphosphine from phosphine that had been generated from calcium phosphide, thereby demonstrating that P2H4 is responsible for spontaneous flammability associated with PH3, and also for the characteristic orange/brown colour that can form on surfaces, which is a polymerisation product. He considered diphosphines formula to be PH2, and thus an intermediate between elemental phosphorus, the higher polymers, and phosphine. Calcium phosphide (nominally Ca3P2) produces more P2H4 than other phosphides because o...More: http: //booksllc.net/?id=264583


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Product Details
  • ISBN-13: 9781157561163
  • Publisher: Books LLC
  • Publisher Imprint: Books LLC
  • Height: 152 mm
  • Sub Title: Phosphine, Duphos, Dimethylphenylphosphine, Triphos, 1,1-Bis(diphenylphosphino)Methane, Tppts, Diphenylphosphine
  • Width: 229 mm
  • ISBN-10: 1157561160
  • Publisher Date: 15 Sep 2010
  • Binding: Paperback
  • Spine Width: 4 mm
  • Weight: 100 gr


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