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Home > Art, Film & Photography > Organotin Compounds: Organotin, Tributyltin, Tetramethyltin, Trimethyltin Chloride, Tributyltin Oxide, Tetrabutyltin, Stannole
Organotin Compounds: Organotin, Tributyltin, Tetramethyltin, Trimethyltin Chloride, Tributyltin Oxide, Tetrabutyltin, Stannole

Organotin Compounds: Organotin, Tributyltin, Tetramethyltin, Trimethyltin Chloride, Tributyltin Oxide, Tetrabutyltin, Stannole


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Chapters: Organotin, Tributyltin, Tetramethyltin, Trimethyltin Chloride, Tributyltin Oxide, Tetrabutyltin, Stannole, Triphenyltin Chloride, Triphenyltin Hydride, Fentin Acetate, Tributyltin Hydride, Dibutyltin Oxide, Tetraethyltin, Triphenyltin Hydroxide, Butyltin Trichloride. Source: Wikipedia. Pages: 18. Not illustrated. Free updates online. Purchase includes a free trial membership in the publisher's book club where you can select from more than a million books without charge. Excerpt: Organotin compounds or stannanes are chemical compounds based on tin with hydrocarbon substituents. Organotin chemistry is part of the wider field of organometallic chemistry. The first organotin compound was diethyltin diiodide, discovered by Edward Frankland in 1849. An organotin compound is commercially applied as a hydrochloric acid scavenger (or heat stabilizer) in polyvinyl chloride and as a biocide. Tributyltin oxide has been extensively used as a wood preservative. Tributyltin compounds are used as marine anti-biofouling agents. Concerns over toxicity of these compounds (some reports describe biological effects to marine life at a concentration of 1 nanogram per liter) have led to a worldwide ban by the International Maritime Organization. n-Butyltin trichloride is used in the production of tin oxide layers on glass bottles by chemical vapor deposition. As an example the organic synthesis of tributyl-stannane: A Grignard reagent is prepared from magnesium turnings and (Z)-2-bromo-5-phenyl-2-pentene in dry tetrahydrofuran and titrated with tributyltin chloride until the solution decolourises. The resulting solution is stirred at room temperature for 1 hour and the solvent is removed in a rotavapor. Diethyl ether is added and the ether extract is washed with brine and filtered and the ether evaporates in a rotavapor. The crude product is kugelrohr distilled to yield tributyl-stannane as a colourless oil. Important reactions involving...More: http: //booksllc.net/?id=186761


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Product Details
  • ISBN-13: 9781157392415
  • Publisher: Books LLC
  • Publisher Imprint: Books LLC
  • Height: 152 mm
  • Sub Title: Organotin, Tributyltin, Tetramethyltin, Trimethyltin Chloride, Tributyltin Oxide, Tetrabutyltin, Stannole
  • Width: 229 mm
  • ISBN-10: 1157392415
  • Publisher Date: 15 Sep 2010
  • Binding: Paperback
  • Spine Width: 1 mm
  • Weight: 45 gr


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