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Crystal Engineering: Metal-Organic Framework

Crystal Engineering: Metal-Organic Framework


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About the Book

Purchase includes free access to book updates online and a free trial membership in the publisher's book club where you can select from more than a million books without charge. Excerpt: Metal-Organic Frameworks are crystalline compounds consisting of metal ions or clusters coordinated to often rigid organic molecules to form one-, two-, or three-dimensional structures that can be porous. In some cases, the pores are stable to elimination of the guest molecules (often solvents) and can be used for the storage of gases such as hydrogen and carbon dioxide. Other possible applications of MOFs are gas purification, gas separation, catalysis and sensors. A metal-organic framework (MOF) is composed of two major components: a metal ion or cluster of metal ions and an organic molecule called a linker. The organic units are typically mono-, di-, tri-, or tetravalent ligands. The choice of metal and linker has significant affects on the structure and properties of the MOF. For example, the metal's coordination preference influences the size and shape of pores by dictating how many ligands can bind to the metal and in which orientation. There is no consensus in the scientific literature about the definitions of the terms coordination polymer and metal-organic framework. Some authors suggests definitions based on chemical bonding others propose that the terms coordination polymer and metal-organic framework are synonyms. An IUPAC project was initiated in 2009 to address the terminology issues in this area and will deliver its final report in 2011. Describing and organizing the complex structures of MOFs could be a difficult and confusing task without a logical, unambiguous set of classifications. Recently, a system of nomenclature has been developed to fill this need. Inorganic sections of a MOF, called secondary building units (SBU), can be described by topologies common to several structures. Each topology, also called a net, is assig... More: http://booksllc.net/?id=9821563


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Product Details
  • ISBN-13: 9781156310601
  • Publisher: Books LLC
  • Publisher Imprint: Books LLC
  • Height: 152 mm
  • Sub Title: Metal-Organic Framework
  • Width: 229 mm
  • ISBN-10: 1156310601
  • Publisher Date: 31 May 2010
  • Binding: Paperback
  • Spine Width: 2 mm
  • Weight: 50 gr


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