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Hypochlorites: Hypochlorous Acid

Hypochlorites: Hypochlorous Acid


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Purchase includes free access to book updates online and a free trial membership in the publisher's book club where you can select from more than a million books without charge. Excerpt: Hypochlorous acid is a weak acid with the chemical formula HClO. In the swimming pool industry, hypochlorous acid is referred to as HOCl. It forms when chlorine dissolves in water. It cannot be isolated in pure form due to rapid equilibration with its precursor (see below). HClO is used as a bleach, an oxidizer, a deodorant, and a disinfectant. Addition of chlorine to water gives both hydrochloric acid (HCl) and hypochlorous acid: Cl2 + H2O HClO + HClWhen acids are added to aqueous salts of hypochlorous acid (such as sodium hypochlorite in commercial bleach solution) this reaction is driven to the left, and chlorine gas is evolved. Thus, the formation of stable hypochlorite bleaches is facilitated by dissolving chlorine gas into basic water solutions, such as sodium hydroxide. Solutions of hypochlorites can be produced by electrolysis of an aqueous chloride solution. Chlorine gas is produced at the anode, while hydrogen forms at the cathode. Some of the chlorine gas produced will dissolve forming hypochlorite ions through the above reaction. The geometry of the cell is critical to ensure that as much of the chlorine as possible dissolves, rather than simply bubbling out of the cell. At the anode: 2Cl Cl2 (g) + 2e At the cathode: 2H + 2e H2 (g) It can be seen that over time, the electrolyte will become increasingly basic. There are a number of potential hazards and challenges associated with this process. It should not be attempted by untrained persons. This is a section stub. See content suggestions. In organic synthesis, HOCl converts alkenes to chlorohydrins. In biology, hypochlorous acid is generated in activated neutrophils by myeloperoxidase-mediated peroxidation of chloride ions, and contributes to the destruction of bacteria and this i... More: http://booksllc.net/?id=578099


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Product Details
  • ISBN-13: 9781156281529
  • Publisher: Books LLC
  • Publisher Imprint: Books LLC
  • Height: 152 mm
  • Sub Title: Hypochlorous Acid
  • Width: 229 mm
  • ISBN-10: 1156281520
  • Publisher Date: 31 May 2010
  • Binding: Paperback
  • Spine Width: 2 mm
  • Weight: 73 gr


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