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Home > Art, Film & Photography > Infrared Spectroscopy: Vibrational Circular Dichroism
Infrared Spectroscopy: Vibrational Circular Dichroism

Infrared Spectroscopy: Vibrational Circular Dichroism


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About the Book

Purchase includes free access to book updates online and a free trial membership in the publisher's book club where you can select from more than a million books without charge. Excerpt: Vibrational circular dichroism (VCD) is a spectroscopic technique which detects differences in attenuation of left and right circularly polarized light passing through a sample. It is basically circular dichroism spectroscopy in the infrared and near infrared ranges. Because VCD is sensitive to the mutual orientation of distinct groups in a molecule, it provides three-dimensional structural information. Thus, it is a powerful technique as VCD spectra of enantiomers can be simulated using ab initio calculations, thereby allowing the identification of absolute configurations of small molecules in solution from VCD spectra. Among such quantum computations of VCD spectra resulting from the chiral properties of small organic molecules are those based on density functional theory (DFT) and gauge-invariant atomic orbitals (GIAO). As a simple example of the experimental results that were obtained by VCD are the spectral data obtained within the carbon-hydrogen (iH) stretching region of 21 amino acids in heavy water solutions. Measurements of vibrational optical activity (VOA) have thus numerous applications, not only for small molecules, but also for large and complex biopolymers such as muscle proteins (myosin, for example) and DNA. While the fundamental quantity associated with the infrared absorption is the dipole strength, the differential absorption is proportional also to the rotational strength, a quantity which depends on both the electric and magnetic dipole transition moments. Sensitivity of the handedness of a molecule toward circularly polarized light results from the form of the rotational strength. Extensive VCD studies have been reported for both polypeptides and several proteins in solution; several recent reviews were also compiled... More: http://booksllc.net/?id=9233359


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Product Details
  • ISBN-13: 9781156218402
  • Publisher: Books LLC
  • Publisher Imprint: Books LLC
  • Height: 152 mm
  • Sub Title: Vibrational Circular Dichroism
  • Width: 229 mm
  • ISBN-10: 1156218403
  • Publisher Date: 31 May 2010
  • Binding: Paperback
  • Spine Width: 3 mm
  • Weight: 77 gr


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