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Home > Art, Film & Photography > Homogeneous Catalysis: Olefin Metathesis, Hydrogenation, Hydroformylation, Wacker Process, Bifunctional Catalyst, Wilkinson's Catalyst
Homogeneous Catalysis: Olefin Metathesis, Hydrogenation, Hydroformylation, Wacker Process, Bifunctional Catalyst, Wilkinson's Catalyst

Homogeneous Catalysis: Olefin Metathesis, Hydrogenation, Hydroformylation, Wacker Process, Bifunctional Catalyst, Wilkinson's Catalyst


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Chapters: Olefin Metathesis, Hydrogenation, Hydroformylation, Wacker Process, Bifunctional Catalyst, Wilkinson's Catalyst, Hydrocyanation, Tetrakis(triphenylphosphine)palladium(0), Tetrakis(triphenylphosphine)platinum(0), Hydroamination, Crabtree's Catalyst, Cyclooctadiene Rhodium Chloride Dimer, Kaminsky Catalyst. Source: Wikipedia. Pages: 70. Not illustrated. Free updates online. Purchase includes a free trial membership in the publisher's book club where you can select from more than a million books without charge. Excerpt: Olefin metathesis or transalkylidenation is an organic reaction that entails redistribution of alkylene fragments by the scission of carbon - carbon double bonds in olefins(Alkenes). Since its discovery, olefin metathesis has gained widespread use in research and industry for making products ranging from medicines and polymers to enhanced fuels. Its advantages include the creation of fewer sideproducts and hazardous wastes. Yves Chauvin, Robert H. Grubbs, and Richard R. Schrock shared the 2005 Nobel Prize in Chemistry for "the development of the metathesis method in organic synthesis." The reaction is catalyzed by metals such as nickel, tungsten, rhenium, ruthenium and molybdenum. The reaction consists of an alkene double bond cleavage, followed by a statistical redistribution of alkylidene fragments. The general scope is outlined by the following scheme: Olefin metathesis was first commercialized in petroleum reformation for the synthesis of higher olefins from the products (-olefins) from the Shell higher olefin process (SHOP) under high pressure and high temperatures. Traditional catalysts are derived from a reaction of the metal halides with alkylation agents for example WCl6-EtOH-EtAlCl2. A metathesis reaction is a chain reaction that begins when a metallocarbene and an olefin react to form a metallacyclobutane. This intermediate then reacts further, decomposing into a new olefin (the product) an...More: http: //booksllc.net/?id=185989


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Product Details
  • ISBN-13: 9781155358826
  • Publisher: Books LLC
  • Publisher Imprint: Books LLC
  • Height: 152 mm
  • Sub Title: Olefin Metathesis, Hydrogenation, Hydroformylation, Wacker Process, Bifunctional Catalyst, Wilkinson's Catalyst
  • Width: 229 mm
  • ISBN-10: 1155358821
  • Publisher Date: 15 Sep 2010
  • Binding: Paperback
  • Spine Width: 4 mm
  • Weight: 118 gr


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