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Home > Art, Film & Photography > Enthalpy: Enthalpy of Vaporization, Enthalpy, Standard Enthalpy Change of Combustion, Standard Enthalpy Change of Formation
Enthalpy: Enthalpy of Vaporization, Enthalpy, Standard Enthalpy Change of Combustion, Standard Enthalpy Change of Formation

Enthalpy: Enthalpy of Vaporization, Enthalpy, Standard Enthalpy Change of Combustion, Standard Enthalpy Change of Formation


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About the Book

Purchase includes free access to book updates online and a free trial membership in the publisher's book club where you can select from more than a million books without charge. Chapters: Enthalpy of Vaporization, Enthalpy, Standard Enthalpy Change of Combustion, Standard Enthalpy Change of Formation, Benson Group Increment Theory, Standard Enthalpy Change of Formation, Enthalpy Change of Solution, Isenthalpic Process, Enthalpy Change of Atomization, Standard Enthalpy Change of Reaction, Standard Enthalpy Change of Neutralisation. Excerpt: Benson Group Increment Theory (BGIT), or Group Increment Theory, uses the experimentally calculated heat of formation for individual groups of atoms to calculate the entire heat of formation for a molecule under investigation. This can be a quick and convenient way to determine theoretical heats of formation without conducting tedious experimentation. Heats of formations are intimately related to bond dissociation energies and thus are important in understanding chemical structure and reactivity. Furthermore, although the theory is old, it still is practically useful as one of the best group additivity methods aside from computational methods such as molecular mechanics . However, the BGIT has its limitations, and thus cannot always predict the precise heat of formation. Origin Benson and Buss originated the BGIT in a 1958 paper. Within this manuscript, Benson and Buss proposed four approximations: These approximations account for the atomic, bond, and group contributions to heat capacity (Cp), enthalpy ( H), and entropy ( S). The most important of these approximations to the group increment theory is the Second Order Approximation, because this approximation "leads to the direct method of writing the properties of a compound as the sum of the properties of its group." The Second Order Approximation accounts for two molecular atoms or structural elements that are within relative proximity to one another (approximately 3-5 A...


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Product Details
  • ISBN-13: 9781155181332
  • Publisher: Books LLC
  • Publisher Imprint: Books LLC
  • Height: 152 mm
  • Sub Title: Enthalpy of Vaporization, Enthalpy, Standard Enthalpy Change of Combustion, Standard Enthalpy Change of Formation
  • Width: 229 mm
  • ISBN-10: 1155181336
  • Publisher Date: 01 May 2010
  • Binding: Paperback
  • Spine Width: 3 mm
  • Weight: 95 gr


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