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Atomic Form with Special Reference to the Configuration of the Carbon Atom

Atomic Form with Special Reference to the Configuration of the Carbon Atom


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About the Book

This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1922 Excerpt: ...and Van't Hoff1 in 1898, quoted the following instructive passage from Pasteur's writings: --"Are the atoms of Tartaric Acid arranged along the spiral of a right-handed screw, or are they situated at the corners of an irregular tetrahedron, or have they some other asymmetric grouping? Time must answer the question. But of this there is no doubt, that the atoms possess an asymmetric arrangement like that of an object and its mirrored image. Equally certain is it that the-atoms of the left-handed acid possess just the opposite asymmetric arrangement." During the sixty years that have passed since these words were written, an enormous amount of study has been given to asymmetric Isomerism, and a mass of detail has been recorded; the subject is still, however, involved in much controversy and speculation, and many problems await solution. "' The Arrangement of Atoms in Space," 2nd Edition, p. 12, (1898), J. H. Van't Hoff. F Stewart, in Stereochemistry, l writes: --"In the purely stereochemical field, much yet remains to be done in the examination of isomeric compounds for the existence of which no explanation can be adduced under current theories." It is claimed for the theory of Atomic Form that right-handed and left-handed spirals are displayed by the carbonoid aggregates when arranged to represent carbon chains, resulting in an asymmetric arrangement like that of an object and its mirrored image. The two spirals are shewn in Fig. 43, p. 66a. The Carbonoid itself is an irregular Tetrahedron, as suggested by Pasteur, and to its special configuration is due the asymmstry of the carbonoid chain and its power of depicting a large number of carbon compounds. With the view of simplifying the discussion of the optical activity of carbon, i...


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Product Details
  • ISBN-13: 9781151903099
  • Publisher: Rarebooksclub.com
  • Publisher Imprint: Rarebooksclub.com
  • Height: 246 mm
  • No of Pages: 32
  • Spine Width: 2 mm
  • Width: 189 mm
  • ISBN-10: 1151903094
  • Publisher Date: 01 May 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Weight: 77 gr


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