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Solutions

Solutions


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About the Book

This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1891 Excerpt: ...grams of salt in 100 grams of water; the diffusion-coefficient of the salt at the head of each column is taken as unity. Potassium Salts 1 5 per cent. salt. 2-9 per cent. salt. The most important result to be drawn from the numbers in these tables is that the rates of diffusion of the acids are related to those of the metals so that all the salts of any specified acid always follow in the same order, whatever the acid may be, and so also, all the salts of any metal follow in the same order, independently of the nature of the metal. The following table may be constructed to show the order of the diffusion-coefficients: --This table exhibits a great resemblance with a corresponding table showing the conductivities of salt-solutions.1 1 These conductivities are fully discussed in a later chapter of Ostwald's Lehrbuch.--Translator. 12. Theory of the phenomena of diffusion.--It has been pointed out already that we must regard the osmotic pressure of the dissolved substance as the impelling force in the phenomena of diffusion. As osmotic pressure is proportional to concentration, it follows at once that the rate of diffusion, which is conditioned by the difference between the osmotic pressures in two adjacent layers, must also be proportional to the difference of the concentrations, as it is stated to be in Fick's fundamental law. W. Nernst1 was the first to attribute the phenomena of diffusion to the osmotic pressure; the following method of calculation is due to him. In a diffusion-cylinder of area q let a portion, x, be measured off along the axis, and let the osmotic pressure in this portion be p. Then the pressure of the quantity of substance in the cross-layer qd x is--q dp. If c is the concentration, i.e. the quantity of substance in grammolecular weights i...


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Product Details
  • ISBN-13: 9781151820693
  • Publisher: Rarebooksclub.com
  • Publisher Imprint: Rarebooksclub.com
  • Height: 246 mm
  • No of Pages: 84
  • Spine Width: 4 mm
  • Width: 189 mm
  • ISBN-10: 1151820695
  • Publisher Date: 01 May 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Weight: 168 gr

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