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Smith's Intermediate Chemistry

Smith's Intermediate Chemistry


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About the Book

This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1922 Excerpt: ...concentration, is reached. Up to this point the sulphate of lead formed by the action of the sulphuric acid produces a crust which protects the metal from further action. When a still more concentrated acid is wanted other methods of driving off the water, such as the cascade system or the Gaillard tower, must be employed. The cascade system consists of a series of small silica or siliconiron basins set over an inclined flue, and so placed that each basin delivers by a spout into the one below. The flue is heated by gas or coke firing at the lower end, and dilute acid is fed continuously into the basin at the top end. As the acid passes from basin to basin, it meets hotter and hotter conditions and becomes more and more concentiated. The Gaillard plant consists essentially of a large hollow tower built of acid-resisting stone, and filled with small fragments of similar material. Dilute acid is sprayed in at the top, and meets hot furnace gases injected in at the bottom. Most of the water contained in the acid is carried off by these gases, and concentrated acid collects at the bottom of the tower. A more convenient method of obtaining very concentrated acid, which avoids the difficulties of evaporation entirely, is to add to the chamber acid the requisite quantity of oleum, prepared by the contact process already described. Commercial sulphuric acid, oil of vitriol, has a specific gravity 1.83-1.84, and contains about 93.5 per cent HjS04. Physical Properties of Sulphuric Acid.--The pure acid is a colorless, oily liquid of sp. gr. 1.84, which freezes to a solid at 10. It mixes with water in all proportions, and much heat (heat of solution, see p. 244) is given out when it dissolves. It boils at 330, but the vapor is largely decomposed into free water and sul...


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Product Details
  • ISBN-13: 9781150596988
  • Publisher: Rarebooksclub.com
  • Publisher Imprint: Rarebooksclub.com
  • Height: 246 mm
  • No of Pages: 160
  • Spine Width: 9 mm
  • Width: 189 mm
  • ISBN-10: 1150596988
  • Publisher Date: 21 May 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Weight: 299 gr


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