The Principles of Qualitative Analysis from the Standpoint of the Theory of Electrolytic Dissociation and the Law of Mass Action
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The Principles of Qualitative Analysis from the Standpoint of the Theory of Electrolytic Dissociation and the Law of Mass Action

The Principles of Qualitative Analysis from the Standpoint of the Theory of Electrolytic Dissociation and the Law of Mass Action


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This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1906 Excerpt: ... GROUP IV. 140. The anions belonging to this group comprise: chloride(CY), bromide-(Br'), iodide-(P), cyanide-(CN'), ferrocyanide(Fe(CN) ""), ferricyanide-(Fe(CN) '"), hypochlorite-(CIO'), sulphocyanate-(SCN'), iodate-(I03') and bromate ion (Br03'). They differ essentially from the anions hitherto dealt with in their reactions with the three typical cathions ( no). Solutions of these anions (in ordinary concentrations) give no precipitates with barium ion, since the solubility products of the corresponding compounds are so large that the supersaturation points of the solutions with respect to these salts are never reached. The silver precipitates are insoluble in nitric acid. This is based upon the fact that the hydrogen compounds of these anions are strongly dissociated and the precipitates are difficultly soluble. Hence saturated solutions of the precipitates contain so small an amount of the anion, for example of CI' from silver chloride, that the reaction: AgCl + H-= Ag+H-Cr, does not occur to a noticeable extent. Hydrocyanic acid is, however, an exception. As was stated in 71 it is proportionately little dissociated. An explanation of the inconsistency, which lies in the fact that silver cyanide is nevertheless practically insoluble in nitric acid, will be given later ( 146). Similarly hypochlorous acid is a weak acid. The silver precipitate obtained from a solution of a hypochlorite is scarcely soluble in nitric acid. The fact that it is not silver hypochlorite, but silver chloride, explains the inconsistency in this case (compare 151, (3)). The silver salts of these ions, as well as of those of the two preceding groups, are soluble in ammonia, thiosulphate and potassium cyanide. The reasons for this have already ...


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Product Details
  • ISBN-13: 9781150520518
  • Publisher: General Books
  • Publisher Imprint: General Books
  • Height: 246 mm
  • No of Pages: 116
  • Spine Width: 6 mm
  • Width: 189 mm
  • ISBN-10: 1150520515
  • Publisher Date: 01 Feb 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Weight: 222 gr


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