The Dynamics of Surfaces; An Introduction to the Study of Biological Surface Phenomena
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The Dynamics of Surfaces; An Introduction to the Study of Biological Surface Phenomena

The Dynamics of Surfaces; An Introduction to the Study of Biological Surface Phenomena


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About the Book

This historic book may have numerous typos and missing text. Purchasers can usually download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1914 edition. Excerpt: ... APPENDIX 22. Kinetics of Surface Reactions.--We have hitherto only studied the reactions which take place at surfaces from the point of view of their final results, without reference to their velocities. We have, in fact, only sought to define the equilibria obtained. According to the general conception of chemical reactions we must assume that the reactions are generally reversible, and consequently equilibrium can only be defined kinetically as the state in which the velocity of reaction in one direction is equal to that in the opposite direction. In the same way, when mechanical adsorption takes place according to the principle of the maximum reduction of surface tension, we can define the point of equilibrium kinetically as follows. When in every short interval of time the number of molecules adsorbed is equal to the number which pass from the adsorption layer into the solution, the system is said to be in equilibrium. The same applies to electrochemical adsorption. Kinetic considerations, have, however, very. little practical significance in these cases, because the changes take place so rapidly that equilibrium is reached instantly or in a very few minutes. There are, however, other reactions which take place at surfaces, which are not connected in any way with the specific properties of the surface. These reactions have been studied principally by Nernst,1 and their nature will be best understood by considering a typical example. If solutions of caustic soda and acetic acid are mixed, a well-known reaction takes place with the formation of sodium acetate and water. The course of this reaction, as of all ionic reactions, is extremely rapid, so that we cannot follow its progress, but only identify its conclusion. But if the...


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Product Details
  • ISBN-13: 9781150401428
  • Publisher: Rarebooksclub.com
  • Publisher Imprint: Rarebooksclub.com
  • Height: 246 mm
  • No of Pages: 108
  • Spine Width: 6 mm
  • Width: 189 mm
  • ISBN-10: 1150401427
  • Publisher Date: 20 May 2014
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Weight: 209 gr


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