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X-Rays and Crystal Structure

X-Rays and Crystal Structure


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This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1915 Excerpt: ...of reflection for the face (100) of each crystal by means of the quantity dfJ/Tf' This quantity has the same value, viz. 1.62, for each member of the series. The constancy of this quantity shows that the crystals form a self-consistent series, since in each case the nature of the spectra, and the angles at which they occur, when compared between themselves, are satisfactorily explained by the structures assigned to the crystals. We are justified in assuming that the structures must at any rate approximate closely to the arrangement of atoms in the crystal. There may be slight distortions of the crystal of which the spectra give no evidence, but at any rate the 'marshalling' of the atoms is as we have represented it to be. This being assumed, we may proceed to calculate the wave length of the radiation we are using. Take a face-centred cubic lattice. The unit cube of the lattice as represented in Fig. 27 (b) has four points associated with it, that is to say, in any given volume of the lattice there are four times as many points as the volume contains cubes. The whole cube has eight corner points, each of which is common, however, to eight cubes in all, so that these points only count as one. The six points on the faces are each common to two cubes, so that they can be reckoned as three, making the total number associated with the cube four. Each of the small cubes of Fig. 27 (b) may be said to be associated with half a point. Passing now to the structures we have found for the various crystals, it follows that, associated with the small cubes, we have respectively KCl NaCl ZnS r CaF2 - - - vi 222 2 Ifm is the mass of a hydrogen atom in grams, M the molecular weight of the substance, the mass associated with unit cube of the structure is MmJ2 ...


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Product Details
  • ISBN-13: 9781130490640
  • Publisher: Rarebooksclub.com
  • Publisher Imprint: Rarebooksclub.com
  • Height: 246 mm
  • No of Pages: 46
  • Spine Width: 3 mm
  • Width: 189 mm
  • ISBN-10: 1130490645
  • Publisher Date: 01 Mar 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Weight: 100 gr


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