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A Text-Book of General Physics; For the Use of Colleges and Scientific Schools

A Text-Book of General Physics; For the Use of Colleges and Scientific Schools


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About the Book

This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1900 Excerpt: ...its atomic mass divided by its valence in the compound electrolyzed. Thus, let q stand for the quantity of electricity which passes any point of the circuit, m the total mass liberated, A the atomic mass of the ion, and V its valence. Then _ (4) m = kq--, where k is a constant depending only on the units employed. If t denote the time of flow of the steady current t, equation 4 may be written k'A. (5) m =--zt = ett, kA by writing e =--. e is called the electro-chemical equivalent. It is found by experiment that one ampere, flowing for one second, deposits 0.001118 gin. of silver. Taking the atomic mass of silver as 108, that is, 0 = 16, the value of k is found to be 1.035(10), from which the electro-chemical equivalents of the other elements may be calculated. Thus, by equation 5, if the atomic mass of copper be taken as 63.64, and its valence as 2, the electro-chemical equivalent of copper is e = 0.0003294 2TM-. 1 ampere 1 sec. 356. Theory of Electrolysis.--The facts of electrolysis are best accounted for by the theory originally proposed by Grotthuss and developed by Clausius. Each molecule of an electrolyte is assumed to be composed of two parts which are oppositely charged, and united by certain bonds usually designated as chemical. These parts may consist either of single atoms as in HC1, or of a group of atoms, which in many reactions behaves like an elementary substance, in that the group may be transferred from one compound to another without loss of identity. NO8 and SO4 are examples of such groups or compound radicals. It further seems probable that the positive ion of the molecule does not remain United to the same individual negative ion, but that there is a frequent change of partners, and that during this interchange some of the ions may remai...


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Product Details
  • ISBN-13: 9781130319606
  • Publisher: Rarebooksclub.com
  • Publisher Imprint: Rarebooksclub.com
  • Height: 246 mm
  • No of Pages: 178
  • Spine Width: 10 mm
  • Width: 189 mm
  • ISBN-10: 1130319601
  • Publisher Date: 01 Mar 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Weight: 327 gr


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