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Coal-Tar and Ammonia Volume 1

Coal-Tar and Ammonia Volume 1


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This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1916 Excerpt: ...the vapours of petroleum, browncoal-tar, wood-tar, benzene, spirits of turpentine, etc, through red-hot tubes. The mode of its formation from other hydrocarbons is illustrated by the following equations, which may serve as examples: --2CTHk-ClH1 + 6H, Tuluaor. CwH, + aCiHs-C H111 + aH, etc., etc. It has been synthetically obtained from toluene-styrene by Kraemer and Spilker (Btr., 1890, pp. 3169 and 3269); other syntheses are those by Bchr and Van Dorp--Ber., 1874, pp. 578 and 753; 1875, p. 17); Perkin and Hodgkinson (/. Chem. Sot., xxxvii., p. 526); Patern6 and Fileti (Btr., 1874, p. 1202); Jackson and White (Amer. Chtm.J., ii., p. 283); Anschutz and Eltzbacher (Ber., 1883, p. 623); and Delaire (ibid., 1895, Ref. p. 748). 'Ann. CMttm. Phmrm., cxxtit., p. 308. - Ber., 186S, p. 49. Its formation from other hydrocarbons can be represented by the following equations: --QHii+QH8=Ci4h10 + 4H. Benzcne+Styrolene. 2xC7H8=C14H10 + 6H. Toluene. ClflHs + 2C, H, = CuH10 + 2H. Naphthalene+Acetylene. Note the natural series: --Benzene, C H C2H; Naphthalene, C, H/;CH; "N: H' Ch/ Anthracene, C0H4X QH, . XCH/ Kohler1 found 35 per cent. anthracene in a product accidentally formed by a violent reaction on overheating the higherboiling fractions of crude carbolic acid, although that product had been obtained from "light oil," and could hardly contain substances which would yield anthracene by a mere splitting-off of the elements of water. He regarded this as a confirmation of K. E. Schulze's theory of the formation of the hydrocarbons of tar from phenols, and also of the statement that the anthracene of coal-tar is for the most part formed during the process of distillation itself; but this view cannot be maintained in face ...


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Product Details
  • ISBN-13: 9781130240542
  • Publisher: Rarebooksclub.com
  • Publisher Imprint: Rarebooksclub.com
  • Height: 246 mm
  • No of Pages: 166
  • Spine Width: 9 mm
  • Width: 189 mm
  • ISBN-10: 1130240541
  • Publisher Date: 01 Mar 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Weight: 308 gr


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