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A Guide to Stereochemistry

A Guide to Stereochemistry


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About the Book

This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1892 Excerpt: ...Its origin was, as we have seen, due to the alleged existence of isomerism among structurally identical oximes, especially benzil-oximes. Now Claus1 maintains that structurally identical benzil-oximes do not exist, and suggests the formulae CsHs.C--C.CsHs CeHt.C=: C.CeHt I II NO NO O OH I-I-y-monoxime. CeHa.C--C.CsHs C-hb.c--C.CeHs CeHe.C--C.CeHB N N N--N N N o o o o o A H H H H H OH a-dioxime. dioxime. y-dioxime. This suggestion threatens the very base of the whole theoretical structure built up by Hantzsch and Werner, Auwers and Meyer. The latter' seek to prove that the threat is vain, but are constrained to admit that stereochemistry has not yet shown why the more stable of the two benzil-monoximes should on further treatment with hydroxylamine yield the most unstable of the three dioximes (j'-monoxime yields p-dioxime, see formulas, pp. 41, 42.) Their opposition has been met by Claus,3 who promises experiments on the subject shortly. Further, the Hantzsch-Werner theory does not cover the whole field. The problem of quinquivalent nitrogen is untouched by it. On this Bischoff4 promises investigations, and suggests for NH4CI a formula in which the four hydrogen atoms are disposed at the base of a pyramid of which the chlorine occupies the apex--CI I /N; HAH H H while for NHa he retains the symmetrical formula in a single plane. The transition is supposed to take place thus: CI I H(8) H, u'ah, !, -3' H(1, / i-H, Jj J: prakt. Chem. 2 44, 312. 3 Ber. d. chem. Ges. 24, 3267. prakt. Chem. 45, x, and 377. Ber. d. chem. Ges. 23, 1967. Vaubel1 has attacked the problem in a new way. He assumes that the carbon atom has the form of a regular tetrahedron, and that the atoms of all elements have the same specific gravity, so that the volume of the nitrogen at.


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Product Details
  • ISBN-13: 9781130135909
  • Publisher: Rarebooksclub.com
  • Publisher Imprint: Rarebooksclub.com
  • Height: 246 mm
  • No of Pages: 32
  • Spine Width: 2 mm
  • Width: 189 mm
  • ISBN-10: 113013590X
  • Publisher Date: 01 Mar 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Weight: 77 gr


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