Fundamentals de Ciencia de Polimeros
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Fundamentals de Ciencia de Polimeros: Un Texto Introductorio

Fundamentals de Ciencia de Polimeros: Un Texto Introductorio


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About the Book

This is a new, basic introduction to polymer science. It is both comprehensive and readable. The authors are leading educators in this field with extensive backgrounds in industrial and academic polymer research. The text starts with a description of the types of microstructures found in polymer materials. This provides an understanding of some of the key features of the various mechanisms of homopolymerization and copolymerization which are discussed in following chapters. Also discussed in these chapters are the kinetics and statistics of polymerization, with a separate chapter on the characterization of chain structure by spectroscopic methods. The next part of the text deals with chain conformation, structure and morphology, leading to a discussion of crystallization, melting and glass transition. The discussion then moves from solid state to solution properties where solution thermodynamics is introduced. This provides the basis for discussion of the measurement of molecular weight by various solution methods. The final chapter deals with mechanical and rheological properties which are discussed from a phenomenological continuum approach and then in terms of a fundamental molecular perspective. Altogether, this new text provides a comprehensive, readable introduction to and overview of polymer science. It is well illustrated with schematics prepared for this text to help in the understanding of key concepts. It will provide a basic understanding of today's polymer science for technical and engineering personnel not already familiar with the subject, and a convenient update and overview for materials scientists.

Table of Contents:
Prefacio, 1. Naturaleza de los Materiales Poliméricos, A. POLIMEROS Y CIENCIA DE POLIMEROS, B. ALGUNAS DEFINICIONES BASICAS. ELEMENTOS DE LA MICROESTRUCTURA DE POLIMEROS, C. PESO MOLECULAR. ALGUNAS OBSERVACIONES INICIALES, D. TEXTOS ADICIONALES, E. APENDICE : ESTRUCTURAS QUIMICAS DE ALGUNOS POLIMEROS COMUNES, 2. Síntesis de Polímeros, A. INTRODUCCION, B. POLIMERIZACION POR ETAPAS, C. POLIMERIZACION EN CADENA O DE ADICION, D. PROCESOS DE POLIMERIZACION, E. TEXTOS ADICIONALES, 3. Cinética de las Polimerizaciones de Adición y por Etapas, A. INTRODUCCION, B. CINETICA DE LA POLIMERIZACION POR ETAPAS, C. CINETICA DE LA POLIMERIZACION RADICALARIA, D. TEXTOS ADICIONALES, 4. Estadística de la Polimerización por Etapas, A. INTRODUCCION, B. ESTADISTICA DE LA POLICONDENSACION LINEAL, C. DISTRIBUCION DE PESO MOLECULAR EN POLIMEROS OBTENIDOS POR CONDENSACION LINEAL, D. POLIMEROS DE CONDENSACION MULTICADENA, E. TEORIA DE LA GELIFICACION, F. RAMIFICACION AL AZAR SIN FORMACION DE RETICULO, G. TEXTOS ADICIONALES, 5. Copolimerización, A. INTRODUCCION GENERAL, B. ECUACION DEL COPOLIMERO, C. RELACIONES DE REACTIVIDAD Y COMPOSICION DEL COPOLIMERO, D. DISTRIBUCION SECUENCIAL EN COPOLIMEROS Y APLICACION DE LA TEORIA DE PROBABILIDADES, E. TEXTOS ADICIONALES, 6. Espectroscopía y Caracterización de la Estructura de Cadena, A. INTRODUCCION, B. FUNDAMENTOS DE ESPECTROSCOPIA, C. ESPECTROSCOPIA INFRARROJA BASICA, D. CARACTERIZACION DE POLIMEROS POR ESPECTROSCOPIA INFRARROJA, E. ESPECTROSCOPIA RMN: BASES, F. CARACTERIZACION DE POLIMEROS POR ESPECTROSCOPIA RMN, G. TEXTOS ADICIONALES, 7. Estructura, A. INTRODUCCION, B. ESTADOS DE LA MATERIA Y ENLACE EN MATERIALES POLIMERICOS, C. CONFORMACIONES O CONFIGURACIONES DE CADENAS POLIMERICAS, D. CADENAS POLIMERICAS DESORDENADAS. EL PROBLEMA DEL VUELO AL AZAR, E. MORFOLOGIA DE POLIMEROS, F. CUESTIONES FINALES. UN BREVE COMENTARIO SOBRE EL TAMAÑO, G. TEXTOS ADICIONALES, 8. Cristalización, Fusión y Transición Vítrea, A. PLANTEAMIENTO GENERAL, B. ALGUNOS CONCEPTOS FUNDAMENTALES, C. ALGUNAS CONSIDERACIONES SOBRE EL EQUILIBRIO, D. CINETICA DE CRISTALIZACION EN POLIMEROS, E. LA TEMPERATURA DE FUSION CRISTALINA, F. LA TEMPERATURA DE TRANSICION VITREA, G. TEXTOS ADICIONALES, 9. Termodinámica de Disoluciones y Mezclas de Polímeros, A. INTRODUCCION, B. LA ENERGIA LIBRE DE MEZCLA, C. COMPORTAMIENTO DE FASES DE DISOLUCIONES Y MEZCLAS DE POLIMEROS, D. DISOLUCIONES DILUIDAS, VOLUMEN EXCLUIDO Y TEMPERATURA THETA, E. TEXTOS ADICIONALES, 10. Peso Molecular y Ramificación de Cadena, A. INTRODUCCION, B. PRESION OSMOTICA Y DETERMINACION DEL PESO MOLECULAR PROMEDIO EN NUMERO, C. DISPERSION DE LUZ EN LA DETERMINACION DEL PESO MOLECULAR PROMEDIO EN PESO, D. VISCOSIMETRIA DE DISOLUCIONES. PESO MOLECULAR PROMEDIO VISCOSO, E. CROMATOGRAFIA DE EXCLUSION POR TAMAÑO (O DE PERMEABILIDAD EN GEL), F. SEC EN LA DETERMINACION DE RAMIFICACION DE CADENA LARGA, G. TEXTOS ADICIONALES, 11. Propiedades Mecánicas y Reológicas, A. INTRODUCCION Y PERSPECTIVA GENERAL, B. BREVE RESUMEN DE ALGUNAS CUESTIONES FUNDAMENTALES, C. COMPORTAMIENTO ESFUERZO-DEFORMACION, D. VISCOSIDAD DE POLIMEROS FUNDIDOS, E. VISCOELASTICIDAD, F. FUNDAMENTO MOLECULAR DEL COMPORTAMIENTO MECANICO, G. FALLO MECANICO, H. TEXTOS ADICIONALES, Indice

About the Author :
The Pennsylvania State University, Universidad del Pais Vasco / Euskal Herriko Unibertsitatea, Spain.

Review :
"This is, quite simply, the best . . . textbook on polymer science I have ever read. Why such strong praise? Because the writing style is colloquial . . . and the whole book screams of the authors' tremendous enthusiasm for the subject. . . . The authors are clearly experienced teachers. . ." --Chemistry in Britain (The Royal Society of Chemistry)


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Product Details
  • ISBN-13: 9781000721546
  • Publisher: Taylor & Francis Ltd
  • Publisher Imprint: CRC Press
  • Language: English
  • No of Pages: 474
  • ISBN-10: 100072154X
  • Publisher Date: 16 Aug 2019
  • Binding: Digital (delivered electronically)
  • No of Pages: 474
  • Sub Title: Un Texto Introductorio


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