About the Book
This book is the second volume in a two-volume compilation on controlled/living radical polymerization. It combines all important aspects of controlled radical polymerization: from synthetic procedures, to rational selection of reaction components, to understanding of the reaction mechanisms, to materials and applications.This book is focused on recent progress in the rapidly developing field of controlled/living radical polymerization. It is a
sequel to ACS Symposium Series 685, 768, 854, 944, 1023, and 1024. Volume 1100 deals with the mechanistic aspects of controlled radical polymerization and describes the recent advances in the most
important techniques, whereas Volume 1101 contains chapters on new materials prepared by controlled radical polymerization as well as applications of these materials.
Table of Contents:
Preface
1. Controlling Polymer Primary Structure Using CRP: Synthesis of Sequence-Controlled and Sequence-Defined Polymers
Mirela Zamfir and Jean-François Lutz
2. RAFT Polymerization: A Powerful Tool for the Synthesis and Study of Oligomers
Meiliana Siauw, Brian S. Hawkett, and Sébastien Perrier
3. New Architectures and Applications of Organoboron Polymers Prepared via Controlled Radical Polymerization
Fei Cheng and Frieder Jäkle
4. Synthesis and Characterization of PE-b-POEGMA Copolymers Prepared by Linear/Hyperbranched Telechelic Polyethylene-Initiated ATRP of Oligo(ethylene glycol) Methacrylates
Pingwei Liu, Weiqiang Lu, Wen-Jun Wang, Bo-Geng Li, Zhibin Ye, and Shiping Zhu
5. Microgel-Core Star Polymers as Functional Compartments for Catalysis and Molecular Recognition
Takaya Terashima and Mitsuo Sawamoto
6. Synthesis and SEC Characterization of Poly(methyl methacrylate) Star Polymers
James A. Burns, David M. Haddleton, and C. Remzi Becer
7. Synthesis of ?-End Functionalized Polymers through Tellurium-Metal Transmetallation Reaction
Eiichi Kayahara and Shigeru Yamago
8. Poly(glycidyl methacrylate-block-styrene) for Photolithographically Patternable Resist Materials
Qin Lou and Devon A. Shipp
9. Nanoscale Functional Patterning of Thin Films Using Block Copolymers Prepared through CRP
Brigitte Voit, Maria Riedel, and Jan Stadermann
10. Synthesis and Characterization of Polyhedral Oligomeric Silsequioxane-Core Star Polystyrene via Nitroxide-Mediated Polymerization
David Glé, Trang N. T. Phan, Valérie Monier, Laurence Charles, Denis Bertin, and Didier Gigmes
11. Polymer?Inorganic Hybrid Materials Using Controlled Radical Polymerization
A. O. Patil, H. Dong, A. H. Tsou, and S. Bodige
12. Applications of Surface Initiated ATRP to the Preparation of Polyelectrolyte Brushes for Antifouling, Adhesion Control, Friction Control
Moyotasu Kobayashi, Yuki Terayama, Tatsuya Ishikawa, Masami Terada, Hiroe Soejima, Daiki Murakami, and Atsushi Takahara
13. Surface Intiated Atom Transfer Radical Polymerizations from Indium Tin Oxide Electrodes: Electrochemistry of Polymer Brushes
Bo Yun Kim, R. Clayton Shallcross, Neal R. Armstrong, Hyo-ju Kim, Woo Jin Chung, Rabindra Sahoo, Kookheon Char, Philip T. Dirlam, Philip J. Costanzo, and Jeffrey Pyun
14. Surface-Functionalized and Surface-Functionalizable Poly(vinylidene fluoride) Membranes via Controlled/Living Radical Polymerization and Click Chemistry
Tao Cai, Koon-Gee Neoh, and En-Tang Kang
15. Grafting of Poly(methyl methacrylate) on the Surface of Cylindrical Mesopores of Ordered Silica via Atom Transfer Radical Polymerization
Liang Cao and Michal Kruk
16. Structuring of Polymer Brushes and Surface Nitroxide Exchange Reactions
Hendrik Wagner, Maike Becker, Lifeng Chi, and Armido Studer
17. Surface Modification of Spherical Particles with Bioactive Glycopolymers
André Pfaff and Axel H. E. Müller
18. Activity Control of Mussel Glue Derived Enzymes: A Study on Thermoresponsive Tyrosinase-PNIPAM Conjugates
Patrick Wilke, William L. A. Brooks, Romina Kühnle, Brent Sumerlin, and Hans G. Börner
19. New Design of Thiol-Responsive Degradable Block Copolymer Micelles as Controlled Drug Delivery Vehicles
Qian Zhang, Samuel Aleksanian, Alexander Cunningham, and Jung Kwon Oh
20. (Nitrilotriacetic Acid)-End-Functionalized Polystyrenes Synthesized by ATRP
Mohammad Abdul Kadir, Hong Y. Cho, Bong-Soo Kim, Young-Rok Kim, Sun-Gu Lee, Unyong Jeong, and Hyun-jong Paik
Editors' Biographies
Indexes
About the Author :
Krzysztof Matyjaszewski is J.C. Warner Professor of Natural Sciences at Carnegie Mellon University in Pittsburgh, USA. His research focus is on macromolecular engineering via controlled/living polymerization techniques. He published 15 books, over 70 book chapters, 700 peer-reviewed publications and holds 40 US patents.
Brent S. Sumerlin is the Harold Jeskey Trustee Associate Professor of Chemistry at Southern Methodist University in Dallas, TX. His research is focused on responsive and water-soluble polymers, controlled polymerization techniques, and the applications of well-defined polymers in drug delivery and self-healing materials. He has published approximately 70 peer-reviewed publications and currently serves on the editorial boards of many of the top polymer journals
Nicolay V. Tsarevsky is Assistant Professor of Chemistry at Southern Methodist University in Dallas, TX. His research interests include polymerization techniques, catalysis, functional materials, particularly for drug delivery applications, and the chemistry of hypervalent iodine compounds. He has published over 65 peer-reviewed papers and book chapters, a textbook, and is co-inventor on several patents.