Metallocene-based Polyolefins, 2 Volume Set: Preparation, Properties, and Technology(Wiley Series in Polymer Science)

In the last three years, research into the nature and strength of metallocene-based materials has exploded. This is the first and only book to provide comprehensive coverage of the developments and advances in the field by such major polyolefin companies as Dow, Exxon, and Montell. The authors begin with overviews of metallocene catalysis and metallocene-based polyolefins, then discuss all areas of the technology, from applications to end-products.

Table of Contents:
Machine derived contents note: Nature Of Metallocene Catalysts

Metallocene Polymerization Catalysts: Past, Present and Future (J. Ewen)

Alkylalumoxanes: Synthesis, Structure and Reactivity (A. Barron)

MAO-free Metallocene Catalysts for Ethylene (Co)Polymerization (L. Resconi, et al.)

Influence of Metallocene Structures on Molecular and Supermolecular Architectures of Polyolefins (D. Fischer, et al.)

Olefin Polymerization by Monocyclopentadienyl Compounds of Titanium, Zirconium and Hafnium (S. Ewart M. Baird)

Molecular Architecture: A New Application Design Process Made Possible by Single-site Catalysts (A. Torres, et al.)

Generation of Cationic Active Species for Olefin Polymerization from ansa-Metallocene Amide Complexes (I. Kim)

Supported Metallocene Polymerization Catalysis (J. Chien)

Supported Metallocene Catalysts for Olefin Polymerization (G. Hlatky)

Homogeneous Phosphametallocene-based Catalysts for Olefin Polymerization (M. Sone)

Nickel- and Palladium-based Catalysts for the Insertion Polymerization of Olefins (L. Johnson C. Killian)

Ethylene Polymerization

Structure, Properties and Preparation of Polyolefins Produced by Single-site Catalyst Technology (P. Chum, et al.)

New Developments in the Production of Metallocene LLDPE by High-pressure Polymerization (A. Akimoto A. Yano)

Metallocenes as Catalysts for the Copolymerization of Ethene with Propene and Oienes (M. Galimberti, et al.)

Copolymerization of Ethylene with Dienes Using Metallocene/MAO Catalysts (G. Jiang)

Ethylene Polymerization Using a Metallocene Catalyst Anchored on Silica with a Spacer (D.-H. Lee S. Noh)

Propylene Polymerization

Synthesis of Isotactic Polypropylene by Metallocene and Related Catalysts (K. Soga, et al.)

Synthesis and Properties of Metallocene Catalysts for Isotactic Polypropylene Production (W. Spaleck)

Properties of Metallocene-catalyzed Isotactic Polypropylene (W. Spaleck)

Metallocene-catalyzed Syndiotactic Polypropylene: Preparation and Properties (T. Shiomura, et al.)

Synthesis of Atactic Polypropylene Using Metallocene Catalysts (L. Resconi)

Design of Ethylene-bridged ansa-Zirconocene Dichlorides for a Controlled Propene Polymerization Reaction (J. Voegele, et al.)

Index

John Scheirs has worked extensively with poly and related polyesters. His early work involved studying the UV stability of PET and poly- ethylene naphthalate - in France and later he was involved with studying various industrial problems involving polyesters, such as photodegradation, annealing, crystallization behaviour, embrittlement, degradation by aminolysis, differential scanning calorimetry analysis, environmental stress cracking, hydrolysis, nucleating agents, transesterification, injection moulding of recycled PET compounds, solid-state polycondensation, desiccant drying of PET and melt stabilization of PET. More recently in the period 1998-2000, he was the technical manager for Coca-Cola Amatil's world-first PET reforming plant which converts post-consumer PET bottles into high-grade, high IV palletized PET for direct reuse in new bottles and injection and sheet moulding applications. John Scheirs is now the principal consultant with ExcelPlas Polymer Technology where he specializes in polymer recycling chemistry, formulation, processing and testing.

Walter Kaminsky is a professor for technical and macromolecular chemistry at the University of Hamburg. He supervises a group of 20 students and scientists in the field of metallocene/MAO catalysis and a group in the field of recycling of plastics and scrap tires by pyrolysis. He was President of the Gesellschaft Deutscher Chemiker - GDCh -, Hamburg section, Dean of the faculty of chemistry at the University of Hamburg, Director of the Institute for Technical and Macromolecular Chemistry, and is a member of the GDCh, DECHEMA, Naturforscher und Årzte, Verein deutscher Ingenieure, and American Chemical Society. He has published more than 200 papers/books and holds 20 patents. He has organized several international symposia in the field of olefin polymerization and pyrolysis of polymer wastes. He is advisor for authorities and companies in the fields of metallocene catalysts, polymerization of olefins, and recycling of plastics and environmental protection.