Internationally renowned authors review recent advances in the understanding of the structure and reactivity of transition metal hydrides. This up-to-date analysis of transition metal hydrides examines the recent upsurge of experimental studies devoted to transition metal hydrides in both gas phase and solution. It also explores the recent emergence of new refinements in the methodologies and techniques used to delineate reaction mechanisms in solution.
Table of Contents:
1. Introduction to Transition Metal Hydrides What is a Transition Metal Hydride?
Importance of Transition Metal Hydrides in Catalysis
Theoretical Approaches to Studying Metal Hydrides (DFT, MO Theory)
2. Electronic Structure and Bonding
Metal-Hydrogen Bond Character
Back-Donation and its Influence on Stability
Factors Affecting Hydride Stability (Metal Oxidation State, Ligand Effects)
3. Structural Features of Transition Metal Hydrides
Coordination Geometry and Hydride Position
X-ray Crystallography and Neutron Diffraction Studies
Spectroscopic Characterization (NMR, IR)
4. Formation of Transition Metal Hydrides Oxidative Addition of H2, Heterolytic Cleavage of H2, and Protonation of a Metal Complex.
5. Reactivity of Transition Metal Hydrides
Insertion Reactions (CO, Olefins)
Reductive Elimination
Hydrogen Transfer Reactions
Beta-Hydride Elimination
6. Catalytic Applications of Transition Metal Hydrides
Hydrogenation Reactions (Alkenes, Alkynes, Carbonyl Compounds)
Hydrosilylation
Hydroboration
Asymmetric Catalysis
7. Selected Case Studies The Wilkins on Catalyst (Rh-based), The Crabtree Catalyst (Ir-based), and Metal Hydrides in Polymerization Reactions.
8. Recent Advances and Future Directions Computational Modeling of Hydride Reactivity, Development of New Catalysts for Hydrogen Storage, and Biomimetic Hydride Transfer Systems.
About the Author :
A. Dedieu is the author of Transition Metal Hydrides, published by Wiley.
