An Introduction to Chemical Crystallography - Bookswagon UAE
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An Introduction to Chemical Crystallography

An Introduction to Chemical Crystallography


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This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated.1906 Excerpt: ... MOLECULAR COMPOUNDS In the preceding section (page 98), it was mentioned that isomorphous mixtures in simple stoichiometric proportions appear in certain cases to possess greater stability than do those in other proportions. Now, the view regarding crystal structure which has been here adopted, shows at once that the formation of a crystal from two different kinds of chemical molecules, even though these differ very slightly from each other, will give a particularly stable structure when the molecules take part in this formation in regularly alternating manner; since such a substance has as much right to the name of "molecular compound" as to that of "isomorphous mixture," it is evident that that view does not permit of any sharp boundary between the two ideas. It is also to be expected that the predilection for definite simple stoichiometric proportions will become more evident the greater the difference between the two constituents replacing one another in the components of the mixture. An example of two substances which, in the narrowest sense of the term, are isomorphous, and yet exhibit peculiar points of greater stability in the series of mixtures which they form, is provided by the two sulphates of magnesium and zinc, investigated by Hollmann (see note, page 98). As regards isomorphism, the two metals magnesium and calcium exhibit greater differences than magnesium and zinc do, and here the predilection for simple stoichiometric proportions appears much more strongly. Calcite, CaC0: l, and magnesite, MgC03, must, from their physical properties (crystalline form, cleavage, etc.), still be described as isomorphous, and there undoubtedly occur mixtures of the two in varying proportions, though in these, as a rule, the one or the other salt preponderates ...


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Product Details
  • ISBN-13: 9780217778848
  • Publisher: General Books
  • Publisher Imprint: General Books
  • Height: 246 mm
  • No of Pages: 54
  • Spine Width: 3 mm
  • Width: 189 mm
  • ISBN-10: 0217778844
  • Publisher Date: 01 Feb 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Weight: 113 gr

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