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Principles of Chemical Kinetics

Principles of Chemical Kinetics


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About the Book

Table of Contents:
Some fundamental ideas of kinetics; rates of reactions; dependence on concentration; cautions on treating kinetics data; effects of temperature; mechanisms of reactions; catalysis; kinetics of more complex systems; second-order case, first-order in two components; other reaction order; parallel first-order reactions; series first-order reactions; reversible reactions; autocatalysis; effect of temperature; techniques and methods; calculating rate constants; method of half-lives; initial rates; flooding; logarithmic method; effects of pressure; flow techniques; tracer methods; kinetic isptope effects; reactions in the gas phase; collision theory; the potential energy surface; transitional state theory; unimolecular decomposition of gases; free radical and chain mechanisms; adsorption; catalysis; reactions in solutions; the nature of liquids; solvent polarity effects on rates; ideal solutions; ideal solution and cohesion energies; effects of solvent cohesion energy on rates; solvation and its effects on rates; effects of ionic strength;linear free-energy relationships; compensation effect; some correlations of rate with solubility parameter; enzyme catalysis; enzyme action; kinetics of reactions catalyzed by enzymes; inhibition of enzyme action; enzyme activation by metal ions; regulatory enzymes; kinetics of reactions in the solid state; general considerations; factors affecting reaction rates in solids; rate laws; the Prout-Tompkins equation; rate laws based on nucleation; kinetic studies; nonisothermal methods in kinetics; TGA and DSCA methods; kinetic analysis by the Coats and Redfern method; the Reich and Stivala method; a method based on three data pairs; a differential method; a comprehensive nonisothermal kinetic method; the general rate law and comprehensive method.


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Product Details
  • ISBN-13: 9780071148313
  • Publisher: McGraw-Hill Education - Europe
  • Publisher Imprint: McGraw-Hill Education (ISE Editions)
  • Height: 230 mm
  • ISBN-10: 0071148310
  • Publisher Date: 01 Aug 1996
  • Binding: Hardback
  • Weight: 518 gr

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