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Proceedings of the Annual Meeting Volume 9

Proceedings of the Annual Meeting Volume 9


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This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1887 Excerpt: ...H2. 4 Fe," 2 C6H50, +3 0, =Fe,"' 03 4 C, H507. Process II. The application of Ferrous Hydrate or Ferrous Carbonate in place of Iron Filings of Process I, Ferrous Hydrate and Ferrous Carbonate being still more inclined to the absorption of Oxygen can not be used for the preparation of the salt. The production of Ferric Citrate being in excess of Ferrous salt. Process III. Decomposition of a normal Citrate of the alkali metals with freshly prepared solution of Ferrous Chloride of definite strength. This method presents many difficulties, in as much as double salts are formed of various degrees of solubility, but all more or less green in color. Ammonium Citrate generated more heat, and the degree of oxidation was more rapid and complete. The salts formed were scaly, green to brown in color, depending upon the ammonia combined, the vapors of which were continually evolved during evaporation. The proper test solutions indicating Ferroic condition. The constitution of the salts could not be determined, but in all probability they are similar to the Potassium and Sodium salts. The Citrates of Potassium and Sodium yielded granular salts, green in color of various degrees of intensity and with no indication of Ferric salt. The Sodium salt being more definite in crystalline structure, the Potassium salt having a tendency to scale. Operating with definite quantities, the salts formed, indicated the following constitution.-f Sodium or ) Citrate and f Di Sodium or ") n-. . Ferrous, j Patassium j Ferrous Di Potassium. Citrate. The reactions being represented by the following symbols: 2 K, C6H60, + 2 Fe Cl2=2 Fe KC6H50, .H20+4 K CI. 2 NasC6H60, --2 Fe Cl2=2 Fe Na QH60, .H20+3 Na CI. 2 K3C, H50, +Fe Cl2=Fe K4 2 CeH60, -2 H20+2 K CI. 2 Na3C6H507+Fe Cl2=Fe Na4 2...


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Product Details
  • ISBN-13: 9781150830693
  • Publisher: Rarebooksclub.com
  • Publisher Imprint: Rarebooksclub.com
  • Height: 246 mm
  • No of Pages: 70
  • Spine Width: 4 mm
  • Width: 189 mm
  • ISBN-10: 1150830697
  • Publisher Date: 01 Mar 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Weight: 141 gr


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